111867-59-5

Basic information

• Product Name: Benzenamine, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-N-[(4-methoxyphenyl)methylene]-
• CAS NO: 111867-59-5
• Molecular Formula: C20H27NO2Si
• Molecular Weight: 341.525
• Mol File: 111867-59-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-N-[(4-methoxyphenyl)methylene]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-N-[(4-methoxyphenyl)methylene]-(111867-59-5)
• EPA Substance Registry System: Benzenamine, 4-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-N-[(4-methoxyphenyl)methylene]-(111867-59-5)

Safety Data

• Hazardous Substances Data: 111867-59-5(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 123-30-8 4-amino-phenol 
• 3230-39-5 4-{[1-(4-Methoxy-phenyl)-meth-(Z)-ylidene]-amino}-phenol 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 101067-57-6 3-phenoxy-4-phenylazetidin-2-one 
• 111761-88-7 cis-1-(p-dimethyl-t-butylsiloxyphenyl)-4-(p-methoxyphenyl)-3-phenoxyazetidin-2-one 

Relevant articles and documents

Reagents and Synthetic Methods. Part 58. Synthesis of β-Lactams from Acetic Acids and Imines promoted by Vilsmeier Type Reagents

The development of a practical method for the stereospecific preparation of several 3-substituted β-lactams from acetic acids and imines is described.The key step of the method is the activation of the carboxy component by means of Vilsmeier type reagents.The preparation of some N-(2'-hydroxyethyl)-β-lactams and N-(p-dimethyl-t-butylsiloxyphenyl)-β-lactams as intermediates for N-H azetidinones is also reported.For the last compounds the steric bulk of the N-substituent is the key feature for a high cis-β-lactam formation.