111874-57-8

Basic information

• Product Name: Benzene, 1-methoxy-4-(1-methoxy-3-butenyl)-
• CAS NO: 111874-57-8
• Molecular Formula: C12H16O2
• Molecular Weight: 192.258
• Mol File: 111874-57-8.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-(1-methoxy-3-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-(1-methoxy-3-butenyl)-(111874-57-8)
• EPA Substance Registry System: Benzene, 1-methoxy-4-(1-methoxy-3-butenyl)-(111874-57-8)

Safety Data

• Hazardous Substances Data: 111874-57-8(Hazardous Substances Data)

Upstream product

• 1515-81-7 1-methoxy-4-(methoxymethyl)benzene 
• 76-63-1 allytriphenyltin 
• 2186-92-7 p-Anisaldehyde dimethyl acetal 
• 762-72-1 allyl-trimethyl-silane 
• 24165-60-4 1-(4-methoxyphenyl)but-3-en-1-ol 
• 74-88-4 methyl iodide 
• 114095-59-9 (1S*, 2S*)-2-((4-methoxyphenyl)cyclopropyl)methanol 
• 123-11-5 4-methoxy-benzaldehyde 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 6142-64-9 (1R*,2R*)-ethyl 2-(4-methoxyphenyl)cyclopropanecarboxylate 
• 106-95-6 allyl bromide 
• 67-56-1 methanol 
• 54835-91-5 trans-<2-(p-methoxyphenyl)cyclopropyl>methyl acetate 
• 105-13-5 4-Methoxybenzyl alcohol 

Downstream Products

• 69098-07-3 3-methoxy-3-(4-methoxyphenyl)propanal 
• 865776-99-4 5-[2-methoxy-2-(4-methoxy-phenyl)-ethyl]-thiazole-4-carboxylic acid methyl ester 
• 865777-08-8 5-[2-methoxy-2-(4-methoxy-phenyl)-ethyl]-thiazole-4-carboxylic acid 
• 865776-90-5 2-amino-5-[2-methoxy-2-(4-methoxy-phenyl)-ethyl]-thiazole-4-carboxylic acid methyl ester 
• 13087-56-4 1-(hepta-1,6-dien-4-yl)-4-methoxybenzene 
• 118167-25-2 C₂₂H₂₆O₂ 

Relevant articles and documents

Iron(III) p-toluenesulfonate catalyzed synthesis of homoallyl ethers from acetals and aldehydes

Iron(III) p-toluenesulfonate, Fe(OTs)3·6H2O, is an inexpensive, versatile and commercially available catalyst for the allylation of acetals using allyltrimethylsilane to yield homoallyl ethers in moderate to good yields. The one-pot

DDQ-induced and stereoselective functionalization at heterosubstituted benzylic positions by carbon nucleophiles

2,3-dichloro-5,6-dicyanobenzoquinone (DDQ) induced functionalization at the heterosubstituted benzylic position with a variety of carbon nucleophiles proceeds in high yield with good stereochemical control.

Scandium as a pre-catalyst for the deoxygenative allylation of benzylic alcohols

Scandium triflate is an effective pre-catalyst for the deoxygenative allylation of benzylic alcohols with a narrow substrate window. The reaction is shown to proceed through a "hidden Br?nsted acid" mechanism. The reaction is efficient provided that the aryl group is neither too electron rich nor too electron poor. It is shown that this allows useful selectivity. The reaction also works for benzyhydryl alcohols with broader scope. The reaction may also be catalysed by Nafion.

Highly efficient triphenyl(3-sulfopropyl)phosphonium functionalized phosphotungstic acid on silica as a solid acid catalyst for selective mono-allylation of acetals

Silica supported phosphotungstic acid functionalized with triphenyl(3-sulfopropyl)phosphonium (PW-Si/TPSP) was developed as a solid acid catalyst for C-C bond formation via Hosomi-Sakurai allylation of acetals. Functionalization of PW as well as its bindi