111905-37-4

Basic information

• Product Name: (μ-(phenyl)CN(phenyl))(μ-methylthiolate)diiron hexacarbonyl
• CAS NO: 111905-37-4
• Molecular Weight: 507.086
• Mol File: 111905-37-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (μ-(phenyl)CN(phenyl))(μ-methylthiolate)diiron hexacarbonyl(CAS DataBase Reference)
• NIST Chemistry Reference: (μ-(phenyl)CN(phenyl))(μ-methylthiolate)diiron hexacarbonyl(111905-37-4)
• EPA Substance Registry System: (μ-(phenyl)CN(phenyl))(μ-methylthiolate)diiron hexacarbonyl(111905-37-4)

Safety Data

• Hazardous Substances Data: 111905-37-4(Hazardous Substances Data)

Upstream product

• 15321-51-4 diiron nonacarbonyl 
• 6780-43-4 S-methyl N-phenylbenzenecarboximidothioate 
• 4903-36-0 N-phenyl-benzimidoyl chloride 
• 17685-52-8 triiron dodecarbonyl 

Relevant articles and documents

Synthesis and characterization of (μ-R1C=NPh)(μ-RS)Fe2(CO)6 complexes

New μ-iminoacyl complexes of the type (μ-R1C=NPh)(μ-RS)Fe2(CO)6 were prepared by the reactions of triiron dodecacarbonyl with thioimidates (R1C(SR)=NPh). The geometry of the bridging iminoacyl and thiolate ligands was determined primarily from IR and 13C NMR spectral correlations to related acyl and thioacyl systems. In related work, reaction of [Et3NH][(μ-Cp)(μ-RS)Fe2CO)6] with N-phenylbenzimidoyl chloride was found to be an alternate and superior route to complexes of this class.