111922-99-7Relevant academic research and scientific papers
A simple synthetic protocol for oxidation of alkyl-arenes into ketones using a combination of HBr-H2O2
Khan, Abu T.,Parvin, Tasneem,Choudhury, Lokman H.,Ghosh, Subrata
, p. 2271 - 2274 (2007/10/03)
A wide variety of alkyl- and cycloalkyl-arenes undergo benzylic C-H oxidation by employing a combination of 48% hydrogen bromide and 30% hydrogen peroxide in dichloromethane at room temperature. In addition, a chemoselective oxidation at the benzylic position is feasible by deactivating the aromatic ring using the same combination.
Oxidative deprotection of 1,3-dithiane group using NaClO2 and NaH2PO4 in aqueous methanol
Ichige, Takahiro,Miyake, Annu,Kanoh, Naoki,Nakata, Masaya
, p. 1686 - 1690 (2007/10/03)
The 1,3-dithiane group was oxidatively deprotected under the conditions of sodium chlorite, sodium dihydrogenphosphate, and 2-methyl-2-butene in 3:1 methanol-water at room temperature in good yield.
Preparation of Nitrobenzaldehydes and Nitrophenyl Ketones by Electrophilic Amination of Nitrobenzyl Aryl Sulfones
Wulf, Jens-Peter,Sienkiewicz, Krzysztof,Makosza, Mieczyslaw,Schmitz, Ernst
, p. 537 - 538 (2007/10/02)
Nitrobenzyl aryl sulfones 1a-g react with 3,3-pentamethylene-oxaziridine (2) with incorporation of an NH group into the benzylic position, followed by cleavage to nitrobenzaldehydes 4a-d and nitrophenyl ketones 4e-g, respectively.
Enamines: Part IV - Synthesis of Nitro Substituted Alkyl Phenyl Ketones
Kulkarni, Sheshgiri N.,Bhamare, N. K.,Kamath, H. V.
, p. 168 - 170 (2007/10/02)
Nitro substituted alkyl phenyl ketones (V) have been synthesised by reacting nitro substituted benzoyl chlorides (II) with morpholine enamines (I) of aliphatic aldehydes.The resulting acylated enamines (III) on hydrolysis afford the desired V.However, 2-n
