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112-23-2

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112-23-2 Usage

Description

Heptyl formate has a fruity-floral odor with an orris-rose undertone and a sweet taste reminiscent of plum. May be synthesized from n-heptyl bromide and formamide at the boil.

Chemical Properties

Different sources of media describe the Chemical Properties of 112-23-2 differently. You can refer to the following data:
1. Heptyl formate has a fruity-foral odor with an orris-rose undertone and a sweet taste reminiscent of plum.
2. Colorless liquid; fruity odor.

Occurrence

Reported found in kumquat peel oil and beer

Uses

Heptyl Formate is a synthetic flavoring agent that is a moderately stable, colorless to light yellow liquid of fruity odor. it should be stored in glass or tin containers. it is used in fruit flavors such as apricot, pear, and plum with applications in beverages, ice cream, candy, and baked goods at 1–4 ppm.

Preparation

From n-heptyl bromide and formamide at the boil.

Hazard

Combustible.

Check Digit Verification of cas no

The CAS Registry Mumber 112-23-2 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 1,1 and 2 respectively; the second part has 2 digits, 2 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 112-23:
(5*1)+(4*1)+(3*2)+(2*2)+(1*3)=22
22 % 10 = 2
So 112-23-2 is a valid CAS Registry Number.
InChI:InChI=1/C8H16O2/c1-2-3-4-5-6-7-10-8-9/h8H,2-7H2,1H3

112-23-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name HEPTYL FORMATE

1.2 Other means of identification

Product number -
Other names Heptanol,formate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Food additives -> Flavoring Agents
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:112-23-2 SDS

112-23-2Relevant articles and documents

Sustainable Co-Synthesis of Glycolic Acid, Formamides and Formates from 1,3-Dihydroxyacetone by a Cu/Al2O3 Catalyst with a Single Active Sites

Dai, Xingchao,Adomeit, Sven,Rabeah, Jabor,Kreyenschulte, Carsten,Brückner, Angelika,Wang, Hongli,Shi, Feng

supporting information, p. 5251 - 5255 (2019/03/07)

Glycolic acid (GA), as important building block of biodegradable polymers, has been synthesized for the first time in excellent yields at room temperature by selective oxidation of 1,3-dihyroxyacetone (DHA) using a cheap supported Cu/Al2O3 catalyst with single active CuII species. By combining EPR spin-trapping and operando ATR-IR experiments, different mechanisms for the co-synthesis of GA, formates, and formamides have been derived, in which .OH radicals formed from H2O2 by a Fenton-like reaction play a key role.

Alkyl Formate Ester Synthesis by a Fungal Baeyer–Villiger Monooxygenase

Ferroni, Felix Martin,Tolmie, Carmien,Smit, Martha Sophia,Opperman, Diederik Johannes

, p. 515 - 517 (2017/03/22)

We investigated Baeyer–Villiger monooxygenase (BVMO)-mediated synthesis of alkyl formate esters, which are important flavor and fragrance products. A recombinant fungal BVMO from Aspergillus flavus was found to transform a selection of aliphatic aldehydes into alkyl formates with high regioselectivity. Near complete conversion of 10 mm octanal was achieved within 8 h with a regiomeric excess of ~80 %. Substrate concentration was found to affect specific activity and regioselectivity of the BVMO, as well as the rate of product autohydrolysis to the primary alcohol. More than 80 % conversion of 50 mm octanal was reached after 72 h (TTN nearly 20 000). Biotransformation on a 200 mL scale under unoptimized conditions gave a space-time yield (STY) of 4.2 g L?1 d?1 (3.4 g L?1 d?1 extracted product).

Nickel-catalyzed hydrosilylation of CO2 in the Presence of Et3B for the synthesis of formic acid and related formates

Gonzalez-Sebastian, Lucero,Flores-Alamo, Marcos,Garcia, Juventino J.

, p. 7186 - 7194 (2014/01/06)

The reaction of CO2 with Et3SiH catalyzed by the nickel complex [(dippe)Ni(μ-H)]2 (1) afforded the reduction products Et3SiOCH2OSiEt3 (12%), Et 3SiOCH3 (3%), and CO, which were characterized by standard spectroscopic methods. Part of the generated CO was found as the complex [(dippe)Ni(CO)]2 (2), which was characterized by single-crystal X-ray diffraction. When the same reaction was carried out in the presence of a Lewis acid, such as Et3B, the hydrosilylation of CO2 efficiently proceeded to give the silyl formate (Et3SiOC(O)H) in high yields (85-89%), at 80 C for 1 h. Further reactivity of the silyl formate to yield formic acid, formamides, and alkyl formates was also investigated.

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