112077-92-6

Basic information

• Product Name: N-ACETOXY-N-ACETYL-ORTHO-TOLUIDINE
• Synonyms: N-ACETOXY-N-ACETYL-ORTHO-TOLUIDINE
• CAS NO: 112077-92-6
• Molecular Formula: C11H13 N O3
• Molecular Weight: 207.23
• Mol File: 112077-92-6.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 287.8°Cat760mmHg
• Flash Point: 127.9°C
• Appearance: /
• Density: 1.168g/cm³
• Vapor Pressure: 0.00243mmHg at 25°C
• Refractive Index: 1.549
• CAS DataBase Reference: N-ACETOXY-N-ACETYL-ORTHO-TOLUIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: N-ACETOXY-N-ACETYL-ORTHO-TOLUIDINE(112077-92-6)
• EPA Substance Registry System: N-ACETOXY-N-ACETYL-ORTHO-TOLUIDINE(112077-92-6)

Safety Data

• Hazardous Substances Data: 112077-92-6(Hazardous Substances Data)

Usage

InChI:InChI=1/C11H13NO3/c1-8-6-4-5-7-11(8)12(9(2)13)15-10(3)14/h4-7H,1-3H3

Upstream product

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Relevant articles and documents

Catalyst-free generation of acyl radicals induced by visible light in water to construct C-N bonds

We describe herein a catalyst-free and redox-neutral photochemical strategy for the direct generation of acyl radicals from α-diketones, and its selective conversion of nitrosoarenes to hydroxyamides or amides with AcOH or NaCl as an additive. The reaction was carried out under mild conditions in water with purple LEDs as the light source. A broad scope of substrates was demonstrated. Mechanistic experiments indicate that α-diketones cleave to give acyl radicals, with hydroxyamides being further reduced to amides.

A novel one pot reductive acetylation of nitroarenes

Nitroarenes are reductively acetylated in one pot to the corres, ponding N-arylacetamides and N-(acetyloxy)-N-arylacetamides with Zn and Ac2O in presence of acidic Al2O3 in dichloromethane at room temperature.