112146-58-4

Upstream product

• 112-85-6 n-docosanoic acid 
• 98-88-4 benzoyl chloride 
• 112146-55-1 methyl (2S)-2-tert-butyldiphenylsilyloxytetracosanoate 
• 112146-54-0 ethyl (2S)-2-acetoxytetracosanoate 
• 54563-86-9 (S)-2-hydroxytetracosanoic acid methyl ester 
• 65-85-0 benzoic acid 

Downstream Products

• 112146-63-1 (2S,3R,4E)-N-(2'R)-2'-tert-butyldiphenylsilyloxytetracosanoylsphingenine 
• 112146-62-0 (2S,3R,4E)-N-(2'R)-2'-tert-butyldiphenylsilyloxytetracosanoyl-1,3-di-O-(1-ethoxyethyl)-sphingenine 
• 64655-47-6 (2S,3R,4E)-N-(2'R)-2'-hydroxytetracosanoylsphingenine 
• 112146-60-8 (2R)-2-tert-butyldiphenylsilyloxytetracosanoic acid 
• 112146-59-5 methyl (2R)-2-tert-butyldiphenylsilyloxytetracosanoate 
• 112146-61-9 methyl (2R)-2-(-)-α-methoxy-α-trifluoromethylphenylacetyloxytetracosanoate 

Relevant academic research and scientific papers

Neurosporaside, a tetraglycosylated sphingolipid from neurospora crassa

The new tetraglycosylceramide neurosporaside (1a) has been isolated from the fungus Neurospora crassa. Neurosporaside is a tetraglycosylated glycosphingolipid characterized by a sugar chain unprecedented among natural glycoconjugates. The structure of neurosporaside was elucidated by extensive spectroscopic analysis and microscale degradation analysis, which allowed full structure elucidation using less than 1 mg of compound.

TOTAL SYNTHESIS OF CEREBROSIDES: (2S,3R,4E)-1-O-β-D-GALACTOPYRANOSYL-N-(2'R AND 2'S)-2'-HYDROXYTETRACOSANOYLSPHINGENINE

Total synthesis of both (2S,3R,4E)-1-O-β-D-galactopyranosyl-N-(2'R)-2'-hydroxytetracosanoylsphingenine 23 and the (2'S) stereoisomer were performed in an unambigous way by employing either (2S,3R,4E)-N-(2'R)-2'-(tert-butyldiphenylsilyloxy)tetracosanoylpsh