112150-07-9

Basic information

• Product Name: Dimethyl-[4-(2,4,6-tri-tert-butyl-phenylphosphanylidenemethyl)-phenyl]-amine
• CAS NO: 112150-07-9
• Molecular Weight: 409.595
• Mol File: 112150-07-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Dimethyl-[4-(2,4,6-tri-tert-butyl-phenylphosphanylidenemethyl)-phenyl]-amine(CAS DataBase Reference)
• NIST Chemistry Reference: Dimethyl-[4-(2,4,6-tri-tert-butyl-phenylphosphanylidenemethyl)-phenyl]-amine(112150-07-9)
• EPA Substance Registry System: Dimethyl-[4-(2,4,6-tri-tert-butyl-phenylphosphanylidenemethyl)-phenyl]-amine(112150-07-9)

Safety Data

• Hazardous Substances Data: 112150-07-9(Hazardous Substances Data)

Upstream product

• 100281-31-0 (E/Z)-(Bromomethylene)(2,4,6-tri-tert-butylphenyl)phosphane 
• 7353-91-5 4-dimethylaminophenylmagnesium bromide 
• 100281-23-0 [(dibromomethylene)(2,4,6-tri-tertbutylphenyl)phosphine] 

Relevant articles and documents

The synthetic potential of C-halophosphaalkenes

Methodologies for the functionalization of phosphaalkenes Mes*P=CHal2 were developed. Lithiation with n-butyllithium yielded carbenoids Mes*P=CLiHal which were reacted with various electrophiles such as acid chlorides, carbonyl compounds, and metal halides. The dihalophosphaalkenes were also converted to monohalophosphaalkenes; the latter proved to be suitable for Stille-type cross coupling reaction with Grignard reagents. New phosphaalkenes of the type (E)-Mes*P=C(H)Ar with a variety of functionalities were obtained in high yield and isomeric purity.