112154-24-2Relevant academic research and scientific papers
Fluoro(nitrile)xenon(II) Cations, RC(*)N-XeF+AsF6- (R = H, CH3, CH2F, C2H5, C2F5, C3F7, or C6F5); Novel Examples of Xenon-Nitrogen Bonds and 129Xe-13C, 129Xe-1H, and 129Xe-14N Nuclear Spin-Spin Couplings
Emara, Adel A. A.,Schrobilgen, Gary J.
, p. 1644 - 1646 (1987)
A new class of Xe-N bonded compound results from the interaction of the electron lone pair of a nitrile with the Lewis acid, XeF+; the cationic adducts, RC(*)N-XeF+, have been derived from the interaction of the appropriate nitrile with either XeF+AsF6- or Xe2F3+AsF6- in anhydrous HF at low temperature and characterized in the solid state by Raman spectroscopy (for R = H and Me) and in HF solution by 129Xe, 19F, 14N, 13C, and 1H n.m.r. spectroscopy.
