Journal of the Chemical Society. Chemical communications p. 1644 - 1646 (1987)
Update date:2022-09-26
Topics:
Emara, Adel A. A.
Schrobilgen, Gary J.
A new class of Xe-N bonded compound results from the interaction of the electron lone pair of a nitrile with the Lewis acid, XeF+; the cationic adducts, RC(*)N-XeF+, have been derived from the interaction of the appropriate nitrile with either XeF+AsF6- or Xe2F3+AsF6- in anhydrous HF at low temperature and characterized in the solid state by Raman spectroscopy (for R = H and Me) and in HF solution by 129Xe, 19F, 14N, 13C, and 1H n.m.r. spectroscopy.
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(1987)
