112219-63-3Relevant articles and documents
Nickel-catalyzed kumada cross-coupling reactions of benzylic sulfonamides
Herbert, Claire A.,Hewitt, Kirsten A.,Jarvo, Elizabeth R.,Matus, Alissa C.
, (2021/10/12)
Herein, we report a Kumada cross-coupling reaction of benzylic sulfonamides. The scope of the transformation includes acyclic and cyclic sulfonamide precursors that cleanly produce highly substituted acyclic fragments. Preliminary data are consistent with a stereospecific mechanism that allows for a diastereoselective reaction.