112289-51-7

Upstream product

• 3554-93-6 benzyl 2-acetamido-2-deoxy-α-D-galactopyranoside 
• 67-64-1 acetone 
• 77-76-9 2,2-dimethoxy-propane 
• 13343-62-9 benzyl 2-acetamido-2-deoxy-α-D-glucopyranoside 
• 141019-70-7 Benzyl-2-acetamido-3,6-di-O-benzoyl-2-desoxy-α-D-galactopyranosid 
• 82827-77-8 Benzyl-2-acetamido-2-desoxy-3,6-di-O-dibenzoyl-α-D-glucopyranosid 
• 100-51-6 benzyl alcohol 
• 72-87-7 N-acetyl-D-galactosamine 
• 141019-69-4 Benzyl-2-acetamido-3,6-di-O-benzoyl-2-desoxy-4-O-(trifluormethylsulfonyl)-α-D-glucopyranosid 

Downstream Products

• 141019-72-9 Benzyl-2-acetamido-2,6-didesoxy-6-iod-3,4-O-isopropyliden-α-D-galactopyranosid 
• 206751-89-5 N-((3aR,4R,6S,7R,7aR)-6-Benzyloxy-4-benzyloxymethyl-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-7-yl)-acetamide 
• 112289-49-3 benzyl 2-acetamido-2,6-dideoxy-6-fluoro-3,4-O-isopropilidene-α-D-galactopyranoside 
• 141019-92-3 Benzyl-2-acetamido-3,4-di-O-acetyl-2-desoxy-6-O-(4,5-epoxypentyl)-α-D-galactopyranosid 
• 141019-91-2 Benzyl-2-acetamido-3,4-di-O-acetyl-2-desoxy-6-O-(2,3-epoxypropyl)-α-D-galactopyranosid 
• 141019-90-1 Benzyl-2-acetamido-3,4-di-O-acetyl-2-desoxy-6-O-(4-pentenyl)-α-D-galactopyranosid 
• 141019-89-8 Benzyl-2-acetamido-3,4-di-O-acetyl-6-O-allyl-2-desoxy-α-D-galactopyranosid 
• 142925-54-0 Benzyl-2-acetamido-2-desoxy-6-O-(4,5-epoxypentyl)-α-D-galactopyranosid 
• 141019-96-7 Benzyl-2-acetamido-2-desoxy-6-O-(4-oxopentyl)-α-D-galactopyranosid 
• 142925-53-9 Benzyl-2-acetamido-2-desoxy-6-O-(2,3-epoxypropyl)-α-D-galactopyranosid 
• 141019-97-8 Benzyl-2-acetamido-2-desoxy-6-O-(4,4-azipentyl)-α-D-galactopyranosid 
• 141019-73-0 Benzyl-2-acetamido-2,6-didesoxy-3,4-O-isopropyliden-α-D-galactopyranosid 
• 81997-63-9 benzyl 2-acetamido-2,6-dideoxy-α-D-galactopyranoside 
• 206751-90-8 Acetic acid (2R,3R,4R,5R,6S)-5-acetylamino-6-benzyloxy-2-benzyloxymethyl-4-hydroxy-tetrahydro-pyran-3-yl ester 

Relevant academic research and scientific papers

Synthesis of O-(2-O-sulfo-α-L-idopyranosyluronic acid)-(1 → 3)-2- acetamido-2-deoxy-4-O-sulfo-D-galactopyranose trisodium salt, a disaccharide fragment of dermatan sulfate

Benzyl 2-acetamido-2-deoxy-α, and β-D-glucopyranoside were converted in high yield into the corresponding D-galacto analogues through a three- step procedure. These later were transformed in a straightforward manner into benzyl 2-acetamido-4-O-acetyl-6-O-benzyl-2-deoxy-α, and β-D- galactopyranoside, respectively, which served as acceptors in glycosylation reactions with variously activated derivatives of methyl 2-O-benzoyl-3,O- benzyl-4-O-chloro-acetyl-L-idopyranuronate. Condensation of the chloride derivative promoted by silver triflate led unexpectedly to the formation of the β-linked disaccharide, whereas the trichloroacetimidoyl derivative afforded the expected α-linked disaccharide in 63% yield. O- Dechloroacetylation of this later, followed by 4-methoxybenzylation at O-4 of the uronic acid moiety, saponification of the esters, O-sulfonation of the free hydroxyls, and catalytic hydrogenation provided the title disaccharide in high yield, as its sodium salt.

Building Units of Oligosaccharides, CII. - Synthesis of Modified Derivatives of 2-Acetamido-2-deoxy-D-galactose for the Examination of Substrate Specifities of Core 1-β3-Gal-Transferase and Core 3-β3-GlcNAc-Transferase Involved in the Biosynthesis of O-Gl

The 2-, 3-, 4-, and 6-deoxy derivatives of benzyl 2-acetamido-2-deoxy-α-D-galactopyranoside (7) have been synthesized to test substrate specifities of glycosyltransferases involved in the biosynthesis of O-glycoproteins.The core 1-β3-Gal-transferase does

FLUORINATED CARBOHYDRATES AS POTENTIAL PLASMA MEMBRANE MODIFIERS AND INHIBITORS. SYNTHESIS OF 2-ACETAMIDO-2,6-DIDEOXY-6-FLUORO-D-GALACTOSE

Reaction of benzyl 2-acetamido-3,4-di-O-benzyl-2-deoxy-6-O-mesyl-α-D-galactopyranoside with cesium fluoride gave benzyl 2-acetamido-3,6-anhydro-4-O-benzyl-2-deoxy-α-D-galactopyranoside instead of the desired 6-fluoro derivative.Acetonation of benzyl 2-ace