112346-55-1

Upstream product

• 127-65-1 chloroamine-T 
• 39573-55-2 (1α,2α,5α,6α)-2,5-Dibrom-7-oxabicyclo<4.1.0>hept-3-en 

Downstream Products

• 76670-68-3 (1S,2S,4S,5S,6R,7R)-5-Bromo-8-(toluene-4-sulfonyl)-3-oxa-8-aza-tricyclo[5.1.0.0^2,4]octan-6-ol 
• 76670-70-7 (1α,2α,4α,5α,7α,8α)-9-(4-Methylphenylsulfonyl)-3,6-dioxa-9-azatetracyclo<6.1.0.0^2,4.0^5,7>nonan 
• 112346-56-2 DL-(1α,2α,4α,5β,6α,7α)-6-Brom-3-(4-methylphenylsulfonyl)-8-oxa-3-azatricyclo<5.1.0.0^2,4>octan-5-ol 

Relevant academic research and scientific papers

cis-/trans--O,N,C-Tris-?-homobenzenes - Syntheses, ?2+?2+?2>Cycloreversions, O,N-Heteronines

For the cis-O,O,N-tris-?-homobenzenes 1a,b three alternative syntheses, ultimately starting from benzene or p-quinone, have been devised.In the course of one of these approaches the radical bromination of (tosylimino)-1,4-cyclohexadiene and the equilibrat

cis-Oxa,aza-σ-homobenzenes. Syntheses,[2+2+2]-cycloreversion reactions

cis-Dioxa,aza-tris-(8) and cis-oxa, aza-bis-σ-homobenzenes (21) have been synthesised. With activation barriers, which clearly support the concerted mechanism, they undergo [2+2+2]-cycloreversion yielding 7H-1,4,7-dioxazonines (9) and 4H-1,4-oxazocines (22), resp.