76670-70-7

Basic information

• Product Name: (1α,2α,4α,5α,7α,8α)-9-(4-Methylphenylsulfonyl)-3,6-dioxa-9-azatetracyclo<6.1.0.0^2,4.0^5,7>nonan
• Synonyms: (1α,2α,4α,5α,7α,8α)-9-(4-Methylphenylsulfonyl)-3,6-dioxa-9-azatetracyclo<6.1.0.0^2,4.0^5,7>nonan
• CAS NO: 76670-70-7
• Molecular Weight: 279.317
• Mol File: 76670-70-7.mol

Chemical Properties

• CAS DataBase Reference: (1α,2α,4α,5α,7α,8α)-9-(4-Methylphenylsulfonyl)-3,6-dioxa-9-azatetracyclo<6.1.0.0^2,4.0^5,7>nonan(CAS DataBase Reference)
• NIST Chemistry Reference: (1α,2α,4α,5α,7α,8α)-9-(4-Methylphenylsulfonyl)-3,6-dioxa-9-azatetracyclo<6.1.0.0^2,4.0^5,7>nonan(76670-70-7)
• EPA Substance Registry System: (1α,2α,4α,5α,7α,8α)-9-(4-Methylphenylsulfonyl)-3,6-dioxa-9-azatetracyclo<6.1.0.0^2,4.0^5,7>nonan(76670-70-7)

Safety Data

• Hazardous Substances Data: 76670-70-7(Hazardous Substances Data)

Upstream product

• 76670-66-1 N-((1R,2R,3S,4R,5S,6S)-2,5-Dibromo-4-hydroxy-7-oxa-bicyclo[4.1.0]hept-3-yl)-4-methyl-benzenesulfonamide 
• 112346-60-8 (1α,2α,5α,6α)-2,5-Dibrom-7-(4-methylphenylsulfonyl)-7-azabicyclo<4.1.0>hept-3-en 
• 112297-34-4 DL-(1α,2β,3α,4α,5β,6α)-3-Brom-5-<(4-methylphenylsulfonyl)amino>-7-oxabicyclo<4.1.0>heptan-2,4-diol 
• 112346-55-1 DL-(1α,2α,3β,4β,5α,6α)-2,5-Dibrom-4-<(4-methylphenylsulfonyl)-amino>-7-oxabicyclo<4.1.0>heptan-3-ol 
• 112297-37-7 DL-(1α,2α,4α,5α,6β,7α)-6-<(4-Methylphenylsulfonyl)amino>-3,8-dioxatricyclo<5.1.0.0^2,4>octan-5-ol 
• 112346-61-9 DL-(1α,2α,3β,6β)-2-Brom-6-<(4-methylphenylsulfonyl)amino>-4-cyclohexen-1,3-diol 
• 39573-55-2 (1α,2α,5α,6α)-2,5-Dibrom-7-oxabicyclo<4.1.0>hept-3-en 
• 127-65-1 chloroamine-T 
• 112319-74-1 DL-(1α,2α,4α,5α,6β,7α)-6-<(4-Methylphenylsulfonyl)amino>-3,8-dioxatricyclo<5.1.0.0^2,4>octan-5-ol-methansulfonat 
• 112297-32-2 (1α,2α,3β,4β,5α,6α)-2,5-Dibrom-7-(4-methylphenylsulfonyl)-7-azabicyclo<4.1.0>heptan-3,4-diol 
• 112346-56-2 DL-(1α,2α,4α,5β,6α,7α)-6-Brom-3-(4-methylphenylsulfonyl)-8-oxa-3-azatricyclo<5.1.0.0^2,4>octan-5-ol 
• 112346-62-0 (1α,2α,4α,5α,7α,8α)-6,9-Bis(4-methylphenylsulfonyl)-3-oxa-6,9-diazatetracyclo<6.1.0.0^2,40^5,7>nonan 
• 76670-68-3 (1S,2S,4S,5S,6R,7R)-5-Bromo-8-(toluene-4-sulfonyl)-3-oxa-8-aza-tricyclo[5.1.0.0^2,4]octan-6-ol 

Downstream Products

• 76670-72-9 (Z,Z,Z)-7-(4-Methylphenylsulfonyl)-7H-1,4,7-dioxazonin 
• 39078-11-0 cis-trisoxirane 

Relevant articles and documents

cis-/trans--O,N,C-Tris-?-homobenzenes - Syntheses, ?2+?2+?2>Cycloreversions, O,N-Heteronines

For the cis-O,O,N-tris-?-homobenzenes 1a,b three alternative syntheses, ultimately starting from benzene or p-quinone, have been devised.In the course of one of these approaches the radical bromination of (tosylimino)-1,4-cyclohexadiene and the equilibrat

"cis-Triaza-tris-?-homobenzenes" ("cis-Benzene Triimine") Syntheses and ?2s + ?2s + ?2s>-Cycloreversions to 4,7-Dihydro-1H-1,4,7-triazonines

cis-Triaza-tris-?-homobenzene ("cis-benzene triimine") (2) has been synthesized from cis-trioxa-tris-?-homobenzene ("cis-benzene trioxide") (1) via threefold epoxide-ring opening with sodium azide, tosylation (92percent chiro-/scyllo-triazido tritosylates

cis-Oxa,aza-σ-homobenzenes. Syntheses,[2+2+2]-cycloreversion reactions

cis-Dioxa,aza-tris-(8) and cis-oxa, aza-bis-σ-homobenzenes (21) have been synthesised. With activation barriers, which clearly support the concerted mechanism, they undergo [2+2+2]-cycloreversion yielding 7H-1,4,7-dioxazonines (9) and 4H-1,4-oxazocines (22), resp.