1124-25-0Relevant articles and documents
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Eschinazi,Pines
, p. 1176 (1956)
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Eschinazi,Bergmann
, p. 5651 (1950)
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Gokhale,P.D. et al.
, p. 1391 - 1393 (1976)
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Amberlyst-15: A reusable heterogeneous catalyst for the dehydration of tertiary alcohols
Frija, Luís M.T.,Afonso, Carlos A.M.
experimental part, p. 7414 - 7421 (2012/09/22)
Tertiary alcohols react under mild conditions in the presence of Amberlyst-15 (dry) (solid-supported sulfonic acid) to give predominantly the most stable alkene in very good yield. The dehydration of tertiary alcohol functionality occurs without observation of rearrangement and polymerization products, and with outstanding substrate tolerance, which include the NHCBz, NHBoc, OSEM, OTBDMS, OBOM and ethylene ketal functional groups. Amberlyst-15 (dry) can be easily recovered from the reaction medium and reused for five cycles, maintaining the catalytic efficiency. In addition, the dehydration can occur under continuous operation.
SYNTHESIS AND THERMOCHEMICAL PARAMETERS OF 1-p-MENTHENE AND 3-p-MENTHENE
Kalechits, G. V.,Luk'yanova, V. A.,Kozina, M. P.,Gal'chenko, G. L.
, p. 169 - 173 (2007/10/02)
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TRANSFORMATIONS OF cis- AND trans-CARENES IN THE PRESENCE OF ZEOLITE CATALYSTS
Kalechits, G. V.,Rusak, M. F.
, p. 1881 - 1884 (2007/10/02)
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