5113-87-1

Basic information

• Product Name: (1R)-(+)-TRANS-ISOLIMONENE
• Synonyms: (3R,6R)-3-ISOPROPENYL-6-METHYLCYCLOHEXENE;(1R)-(+)-TRANS-ISOLIMONENE;1R-TRANS ISOLIMONENE;ISOLIMONENE, 1R-TRANS;(+)-P-MENTHA-2,8-DIENE;(+)-(1R,4R)-trans-Isolimonene;(+)-3R-trans-Isolimonene;(+)-trans-Isolimonene
• CAS NO: 5113-87-1
• Molecular Formula: C₁₀H₁₆
• Molecular Weight: 136.23
• EINECS: 225-843-3
• Mol File: 5113-87-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 165-166 °C(lit.)
• Flash Point: 39 °C
• Appearance: /
• Density: 0.83 g/mL at 20 °C(lit.)
• Vapor Pressure: 2.26mmHg at 25°C
• Refractive Index: n20/D 1.47(lit.)
• BRN: 2073245
• CAS DataBase Reference: (1R)-(+)-TRANS-ISOLIMONENE(CAS DataBase Reference)
• NIST Chemistry Reference: (1R)-(+)-TRANS-ISOLIMONENE(5113-87-1)
• EPA Substance Registry System: (1R)-(+)-TRANS-ISOLIMONENE(5113-87-1)

Safety Data

• Hazard Codes: Xn,N
• Statements: 10-51/53-22
• Safety Statements: 61
• RIDADR: UN 1169 3/PG 3
• WGK Germany: 3
• HazardClass: 3.2
• PackingGroup: III
• Hazardous Substances Data: 5113-87-1(Hazardous Substances Data)

Usage

General Description

(1R)-(+)-trans-Isolimonene is a natural organic compound that belongs to the class of terpenes. It is commonly found in various citrus fruits and is responsible for their characteristic citrusy aroma. This chemical is used in the production of perfumes, flavorings, and as an additive in skin care and cleaning products. It has been shown to have anti-inflammatory and antioxidant properties, making it potentially beneficial for skin health. Additionally, (1R)-(+)-trans-Isolimonene has demonstrated antimicrobial activity against certain pathogens. Overall, this chemical compound has a wide range of applications and potential health benefits, making it a valuable ingredient in various industries.

InChI:InChI=1/C10H16/c1-8(2)10-6-4-9(3)5-7-10/h4,6,9-10H,1,5,7H2,2-3H3/t9-,10-/m0/s1

Upstream product

• 4497-92-1 2-carene 
• 67-56-1 methanol 
• 7786-67-6 isopulegol 
• 141277-82-9 ethyl (E)-2-[(2R,5R)-2-methyl-5-(prop-1-en-2-yl)cyclohexylidene]acetate 
• 5524-05-0 (2R,5R)-5-isopropenyl-2-methylcyclohexanone 
• 18142-34-2 2-trans-Amino-3-ref-(CH₃)-trans-caran 

Downstream Products

• 55768-28-0 (3R,6R)-3-Methyl-6-(1-methyl-cyclopropyl)-cyclohexene 
• 99-86-5 1-methyl-4-isopropyl-1,3-cyclohexadiene 
• 99-87-6 4-methylisopropylbenzene 
• 586-67-4 3,8-p-Menthadien 
• 99-85-4 crithmene 
• 586-63-0 isoterpinolene 
• 1062245-86-6 1S-acetyl-4R-methyl-2-cyclohexene 
• 1062245-83-3 1R-acetyl-4R-methyl-2-cyclohexene 
• 1062245-89-9 1R,4R-p-menth-2-en-9-al 
• 5114-00-1 trans-p-menthan-8-ol 
• 5113-94-0 (E)-2-methyl-2-(4-methylcyclohexyl)ethanol 
• 503272-14-8 (R)-2-{(1S,2S,3S,4R)-2-Hydroxy-4-methyl-3-[2-(2-methyl-[1,3]dithiolan-2-yl)-ethyl]-cyclohexyl}-propionic acid methyl ester 
• 503272-16-0 (R)-2-{(1S,3S,4R)-2-[1-Methoxy-meth-(E)-ylidene]-4-methyl-3-[2-(2-methyl-[1,3]dithiolan-2-yl)-ethyl]-cyclohexyl}-propionic acid methyl ester 
• 503272-15-9 (R)-2-{(1S,3S,4R)-4-Methyl-3-[2-(2-methyl-[1,3]dithiolan-2-yl)-ethyl]-2-oxo-cyclohexyl}-propionic acid methyl ester 

Relevant articles and documents

Synthesis of novel methoxyether derivative of isopulegol in a packed-bed flow reactor

8–Methoxymenthan–3–ol was synthesised in a packed-bed flow reactor by the reaction of isopulegol and methanol in the presence of amberlyst-15 dry hydrogen form catalyst. Key parameters that affect isopulegol conversion and 8–methoxymenthan–3–ol formation were investigated and optimised. The reaction was found to be highly temperature-dependent, and to be less dependent of isopulegol: methanol molar ratio. Higher temperatures coupled with rapid flow rates resulted in higher isopulegol conversion. The optimum working temperature in the reactor was 57 °C and a maximum yield of 51.8% of 8–methoxymenthan–3–ol was obtained in 27.4 min at a flow rate of 3.6 cm3/min. Graphic abstract: [Figure not available: see fulltext.]

Liquid-phase noncatalytic oxidation of monoterpenoids with nitrous oxide

A series of monoterpenoids differing in the number of double bonds and the pattern of their substitution were tested in the liquid-phase noncatalytic oxidation with nitrous oxide (N2O). The structure of olefins has a significant effect on the oxidation route. In the case of terpenoids containing 1,1-disubstituted double bond, nor-carbonyl compounds are formed with high selectivity.