112456-83-4Relevant academic research and scientific papers
TOTAL SYNTHESIS OF THE GERMACRANOLIDE (+/-)-ARISTOLACTONE VIA WITTIG RING CONTRACTION
Marshall, James A.,Lebreton, Jacques,DeHoff, Bradley S.,Jenson, Todd M.
, p. 723 - 726 (1987)
The total synthesis of (+/-)-aristolactone (15) is described wherein the key cyclodecenynol precursor 10 is prepared in over 90 percent yield via a highly regio and stereoselective Wittig reaarangement of the 13-membered propargylic ether 9.
