TOTAL SYNTHESIS OF THE GERMACRANOLIDE (+/-)-ARISTOLACTONE VIA WITTIG RING CONTRACTION

DOI: 10.1016/S0040-4039(01)80972-2

Source and publish data:

Tetrahedron Letters p. 723 - 726 (1987)

Update date:2022-07-29

Topics:

Authors:

Marshall, James A.

Lebreton, Jacques

DeHoff, Bradley S.

Jenson, Todd M.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)80972-2

The total synthesis of (+/-)-aristolactone (15) is described wherein the key cyclodecenynol precursor 10 is prepared in over 90 percent yield via a highly regio and stereoselective <2,3> Wittig reaarangement of the 13-membered propargylic ether 9.

Full text of DOI:10.1016/S0040-4039(01)80972-2

Products guided by the article

Product name:Benzoic acid (E)-(1R,10S)-10-isopropenyl-7-methyl-cyclodec-6-en-2-ynyl ester

Cas No:112456-83-4

R&D Labs maybe for 112456-83-4

Nanjing Spring & Autumn Biological Engineering Co., Ltd.

Contact:86-180510-83338

Address:Suite# 210, No. 1 BuildingNanjing Agricultural Biotechnology High-tech Entrepreneurship Center, No. 4 Tongwei Road, Xuanwu District, Nanjing,China
Hangzhou Bayee Chemical Co.,Ltd.

Contact:+86-571-86990109

Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Hangzhou Share Chemical Co., Ltd(expird)

Contact:+86-57187093700

Address:Hang Xing Road
Allicon Pharmaceuticals,Inc.

Contact:+86-519-86339586，13584329896

Address:Changzhou Scientific and Education Park
Shanghai Minstar Chemical Co., Ltd

website:http://www.minstargroup.com

Contact:86-21-18019205509

Address:BUILDING 8, NO.1098, CHUANSHA ROAD, SHANGHAI, CHINA

Relevant to this article

Silyl Enol Ethers Bearing Stereogenic Silicon Atoms and Chiral Alkoxy Groups: The Effect of These Groups upon the Facial Selectivity of the Epoxidation of an Enol Double Bond

Doi:10.1021/jo00239a057
(1988)
Synthesis and magnetic study of μ_1,1-azido-bridged dinuclear manganese(II) complexes based on tripyridyl ligands

Doi:10.1002/ejic.200700680
(2007)
SYNTHESES OF 1-PHENYL-2-(4-PYRIMIDINYL)ETHANONE AND RELATED ETHANONES.

Doi:10.1021/je00052a045
(1988)
Design and synthesis of potent pyridazine inhibitors of p38 MAP kinase

Doi:10.1016/j.bmcl.2005.02.010
(2005)
Synthesis of the hydrazones of 2-((3,5-di-tert-butyl-4-hydroxybenzyl) thio) acetohydrazide and the study of their radical scavenging activity by the DPPH assay and the computational method

Doi:10.1002/bkcs.10553
(2015)
Direct asymmetric Michael addition of thioether-based aryl sulfanyl-propan-2-one to nitroalkenes catalyzed by a chiral amine-thiourea bifunctional organocatalyst

Doi:10.1002/chir.20689
(2010)

Article Doi