112463-02-2

Upstream product

• 138565-92-1 methyl (2RS,5S)-5-(tert-butyldimethylsilyloxy)-2-ethoxypiperidine-1-carboxylate 
• 112462-96-1 (R)-2-((S)-5,5-Dimethoxy-piperidin-2-yl)-1-phenyl-ethanol 
• 112463-01-1 (R)-2-((R)-5,5-Dimethoxy-1-methyl-piperidin-2-yl)-1-phenyl-ethanol 
• 112571-54-7 (3R,4aR)-7,7-Dimethoxy-3-phenyl-hexahydro-pyrido[1,2-c][1,3]oxazine 
• 112530-63-9 (R)-2-((R)-5,5-Dimethoxy-piperidin-2-yl)-1-phenyl-ethanol 
• 112530-62-8 (S)-2-((R)-5,5-Dimethoxy-piperidin-2-yl)-1-phenyl-ethanol 
• 165674-71-5 Methyl (2R,5R,2'R)-5-hydroxy-2-(2-hydroxy-2-phenylethyl)piperidine-1-carboxylate 
• 112462-99-4 (3R,6S)-6-((R)-2-Hydroxy-2-phenyl-ethyl)-piperidin-3-ol 
• 112462-90-5 1-Ethyl-3,3-dimethoxy-piperidine 
• 100-42-5 styrene 
• 112462-99-4 (3S,6S)-6-((R)-2-Hydroxy-2-phenyl-ethyl)-piperidin-3-ol 
• 112462-91-6 3,3-Dimethoxy-piperidin-1-ol 
• 112462-94-9 (2R,3aS)-6,6-Dimethoxy-2-phenyl-hexahydro-isoxazolo[2,3-a]pyridine 
• 165674-70-4 Methyl (2R,5R)-5-acetoxy-2-(2-oxo-2-phenylethyl)piperidine-1-carboxylate 

Downstream Products

• 112463-04-4 (+)-Di-O-acetylhydroxysedamine 

Relevant academic research and scientific papers

Synthesis of (+)- and (-)-Hydroxysedamine and (+)-N-Methylpseudoconhydrine from (S)-Glutamic Acid via Homochiral Acyliminium Ion

Efficient syntheses of (+)-N-methylpseudoconhydrine (5) and (-)-hydroxysedamine (10) are described starting from the readily available (2RS,5S)-Methyl 5-(tert-butyldimethylsilyloxy)-2-ethoxypiperidine-1-carboxylate (1) and proceeding via homochiral acylim

SEDUM ALKALOIDS. X. STRUCTURE AND SYNTHESIS OF NEW 3- AND 5-HYDROXYPIPERIDINE ALKALOIDS.

The structure and absolute configuration of (-)-3-hydroxynorallosedamine 1, (-)-3-hydroxyallosedamine 2 and (-)-5-hydroxysedamine 3, three new minor alklaloids isolated from Sedum acre, are reported.A nitrone-based synthesis of the new bases is described.