112471-71-3Relevant academic research and scientific papers
Metal-free photocatalytic thiol-ene/thiol-yne reactions
Kaur, Sarbjeet,Zhao, Gaoyuan,Busch, Evan,Wang, Ting
supporting information, p. 1955 - 1961 (2019/02/20)
The organic photocatalyst (9-mesityl-10-methylacridinum tetrafluoroborate) in the presence of visible light is used to initiate thiol-ene and thiol-yne reactions. Thiyl radicals are generated upon quenching the photoexcited catalyst with a range of thiols
Air Oxidative Radical Oxysulfurization of Alkynes Leading to α-Thioaldehydes
Zhou, Shao-Fang,Pan, Xiang-Qiang,Zhou, Zhi-Hao,Shoberu, Adedamola,Zhang, Pei-Zhi,Zou, Jian-Ping
, p. 5348 - 5354 (2015/05/27)
Air oxidative radical oxysulfurization of alkynes initiated by 0.5 mol % tert-butyl hydroperoxide with arylthiols is described. The reaction proceeded at room temperature in the presence of 5% mol water to afford selective α-thioaldehydes. (Chemical Equation Presented).
Ruthenium-catalyzed cross-metathesis with electron-rich phenyl vinyl sulfide enables access to 2,3-dideoxy-d-ribopyranose ring system donors
Boutureira, Omar,Isabel Matheu,Diaz, Yolanda,Castillon, Sergio
, p. 19794 - 19799 (2014/05/20)
2,3-Dideoxy-d-ribopyranose units are important ring systems found in nature. Herein, we develop a metal-mediated strategy to form this important scaffold featuring a cross-metathesis reaction of the corresponding sugar-derived hydroxyalkene with electron-
Synthesis of vinyl sulfides under base-free conditions using selenium ionic liquid
Thurow, Samuel,Ostosi, Naiana T.,Mendes, Samuel R.,Jacob, Raquel G.,Lenard?o, Eder J.
experimental part, p. 2651 - 2653 (2012/06/30)
A very simple procedure is described for the efficient synthesis of vinyl sulfides by hydrothiolation of terminal alkynes using 1-n-butyl-3- methylimidazolium methylselenite, [bmim][SeO2(OCH3)]. The reaction proceeds cleanly under mi
Synthesis of vinyl sulfides using glycerol as a recyclable solvent
Lenardao, Eder J.,Silva, Marcio S.,Lara, Renata G.,Marczewski, Junior M.,Sachini, Maraisa,Jacob, Raquel G.,Alves, Diego,Perin, Gelson
experimental part, p. 272 - 282 (2011/05/13)
A new, clean, and efficient protocol is described for the hydrothiolation of terminal alkynes promoted by KF/Al2O3, using glycerol as recyclable solvent. This improved method furnishes selectively the corresponding anti-Markovnikov v
