112621-27-9

Basic information

• Product Name: 1,3-Cyclopentanedione, 2-[(4-hydroxyphenyl)methyl]-2-methyl-
• CAS NO: 112621-27-9
• Molecular Formula: C13H14O3
• Molecular Weight: 218.252
• Mol File: 112621-27-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1,3-Cyclopentanedione, 2-[(4-hydroxyphenyl)methyl]-2-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Cyclopentanedione, 2-[(4-hydroxyphenyl)methyl]-2-methyl-(112621-27-9)
• EPA Substance Registry System: 1,3-Cyclopentanedione, 2-[(4-hydroxyphenyl)methyl]-2-methyl-(112621-27-9)

Safety Data

• Hazardous Substances Data: 112621-27-9(Hazardous Substances Data)

Upstream product

• 80767-12-0 4-hydroxybenzyl acetate 
• 51467-21-1 Sodium salt of 2-Methyl-1,3-cyclopentadione 
• 765-69-5 2-Methylcyclopentane-1,3-dione 
• 623-05-2 (4-hydroxyphenyl)methanol 

Relevant articles and documents

Design, synthesis and application of spiro[4.5]cyclohexadienonesviaone-pot sequentialp-hydroxybenzylation/oxidative dearomatization

One-pot sequentialp-hydroxybenzylation/oxidative dearomatization/spiroannulation has been designed for the efficient construction of tetrahydrofuran containing spiro-cyclohexadienones. This reaction proceeds through thep-hydroxybenzylation of 1,3-diketones withp-hydroxybenzyl alcoholviaquinone methide formation followed by oxidative dearomatization/spiroannulation with suitable alcohols. The Friedel-Crafts alkylation of spiro[4.5]cyclohexadienones with indoles provided a broad array of highly diastereoselective C-3 alkylated spirocycles and cyclohepta[b]indoles depending upon the ring size of the fused cyclic ketones.

Quinone Methide p-Hydroxybenzylation of 1,3-Diketones

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