80767-12-0

Basic information

• Product Name: Benzenemethanol, 4-hydroxy-, a-acetate
• Synonyms: 4-hydroxybenzyl acetate;4-Oxy-11-acetoxy-1-methyl-benzol;4-Acetoxymethyl-phenol;(4-Oxy-benzyl)-acetate;acetic acid 4-hydroxy-benzyl ester;4-acetoxymethylphenol
• CAS NO: 80767-12-0
• Molecular Formula: C9H10O3
• Molecular Weight: 166.177
• Mol File: 80767-12-0.mol
• Article Data: 32

Chemical Properties

• Melting Point: 50 °C
• Boiling Point: 272.2±15.0 °C(Predicted)
• Density: 1.181±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzenemethanol, 4-hydroxy-, a-acetate(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenemethanol, 4-hydroxy-, a-acetate(80767-12-0)
• EPA Substance Registry System: Benzenemethanol, 4-hydroxy-, a-acetate(80767-12-0)

Safety Data

• Hazardous Substances Data: 80767-12-0(Hazardous Substances Data)

Upstream product

• 623-05-2 (4-hydroxyphenyl)methanol 
• 64-19-7 acetic acid 
• 141-78-6 ethyl acetate 
• 116748-05-1 4-(tert-butyldiphenylsilyloxy)benzaldehyde 
• 116748-06-2 (4-(hydroxymethyl)phenoxy)(tert-butyl)diphenylsilane 
• 106-44-5 p-cresol 
• 128-37-0 2,6-di-tert-butyl-4-methyl-phenol 
• 848826-75-5 {2-[(4-hydroxymethyl-phenoxycarbonyl)-methyl-amino]-ethyl}-methyl-carbamic acid tert-butyl ester 
• 1443515-45-4 C₁₉H₂₈N₂O₆ 
• 1443515-47-6 C₁₄H₂₀N₂O₄*C₂HF₃O₂ 
• 1443515-64-7 C₅₃H₆₈N₈O₁₆*C₂HF₃O₂ 
• 1443515-60-3 C₂₇H₃₆N₄O₈*C₂HF₃O₂ 
• 123-08-0 4-hydroxy-benzaldehyde 
• 75-36-5 acetyl chloride 

Downstream Products

• 848245-33-0 2-(4-hydroxy-benzyl)-2-methoxy-malonic acid dimethyl ester 
• 623-05-2 (4-hydroxyphenyl)methanol 
• 53565-75-6 4-(phenylimino-methyl)-phenol 
• 5355-17-9 4-hydroxybenzyl methyl ether 
• 773873-35-1 4-(hydroxymethyl)phenyl propionate 
• 6309-46-2 4-acetoxybenzyl alcohol 
• 1092474-60-6 4-propionyloxybenzyl propionate 
• 1092474-62-8 4-hydroxybenzyl octanoate 
• 386263-85-0 4-hydroxybenzyl propionate 
• 502-87-4 4-methylene-cyclohexa-2,5-dienone 
• 1419942-41-8 C₁₄H₁₁NO₇ 
• 881181-55-1 acetic acid 4-oxo-1-(2-oxoethoxy)cyclohexa-2,5-dienylmethyl ester 
• 941282-79-7 acetic acid 1-(2-hydroxy-ethoxy)-4-oxo-cyclohexa-2,5-dienylmethyl ester 
• 66287-29-4 4-(2,4-dichlorophenoxy-methyl)-phenol 

Relevant articles and documents

Lipase-mediated selective acetylation of primary alcohols in ethyl acetate

An environmental friendly process to selectively acetylate primary alcohols was demonstrated. The esterification process consists of treatment of a primary alcohol in the presence of immobilized C. antarctica lipase (Novozyme-435) in ethyl acetate at room temperature. Primary alcohols were acetylated in the presence of secondary alcohols and phenols.

Decarboxylative Csp3-Csp3 coupling for benzylation of unstable ketone enolates: Synthesis of: P -(acylethyl)phenols

A new decarboxylative Csp3-Csp3 coupling approach for the benzylation of ketone enolates has been developed. A variety of raspberry ketone derivatives were conveniently synthesized in good to excellent yields under mild conditions. A crossover reaction shed light on the mechanism of this tandem reaction.

Efficient approach for the chemoselective acetylation of alcohols catalyzed by a novel metal oxide nanocatalyst CuO-ZnO

A new method has been developed for the chemoselective acetylation of alcohols with acetic anhydride in the presence of phenols using a novel, recyclable CuO-ZnO nanocatalyst. The catalyst was synthesized using the co-precipitation method and characterized by N2 adsorption-desorption, X-ray diffraction, scanning electron microscopy, transmission electron microscopy and energy dispersion scanning analyses. Furthermore, this catalyst could be recycled up to six times without significant loss in its activity.