112658-89-6

Upstream product

• 401636-52-0 di-tert-butyl 4-benzyl-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate 
• 1557159-22-4 1-([1,1'-biphenyl]-4-ylethynyl)-1,2-benziodoxol-3(1H)-one 
• 100-51-6 benzyl alcohol 
• 92-66-0 4-bromo-1,1'-biphenyl 
• 13326-10-8 benzyl methyl carbonate 
• 1024-41-5 benzyl tosylate 

Downstream Products

• 43008-86-2 4-(3-Phenyl-propyl)-biphenyl 
• 102467-39-0 (+/-)-1-biphenyl-4-yl-3-phenyl-propadiene 
• 102467-39-0 (+)-1-biphenyl-4-yl-3-phenyl-propadiene 

Relevant academic research and scientific papers

Application of Hantzsch Ester and Meyer Nitrile in Radical Alkynylation Reactions

The first example of constructing a Csp3-Csp bond with substituted Hantzsch ester and Meyer nitrile is reported. When benziodoxole-activated alkyne was applied as the alkynyl donor, products containing Csp3-Csp bonds involving primary, secondary, and tertiary carbon centers were achieved in up to 97% yields. K2S2O8 was the optimum radical initiator in this reaction.

Cleavage of C–C and C–O Bonds to Form C–C Bonds: Direct Cross-Coupling between Acetylenic Alcohols and Benzylic Carbonates

A palladium-catalyzed cross-coupling reaction between C(sp) and C(sp3) centers was achieved in excellent yields via C–C bond cleavage and C–O bond cleavage. This procedure uses relatively stable acetylenic alcohols as reactants instead of unsta