112661-59-3

Basic information

• Product Name: stolonidiol
• Synonyms: stolonidiol
• CAS NO: 112661-59-3
• Molecular Formula: C20H32O4
• Molecular Weight: 336.47
• Mol File: 112661-59-3.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 468.6°Cat760mmHg
• Flash Point: 237.2°C
• Appearance: /
• Density: 1.16g/cm³
• Vapor Pressure: 9.51E-11mmHg at 25°C
• Refractive Index: 1.555
• CAS DataBase Reference: stolonidiol(CAS DataBase Reference)
• NIST Chemistry Reference: stolonidiol(112661-59-3)
• EPA Substance Registry System: stolonidiol(112661-59-3)

Safety Data

• Hazardous Substances Data: 112661-59-3(Hazardous Substances Data)

Usage

InChI:InChI=1/C20H32O4/c1-13-5-6-15-19(12-21,23-15)11-16-20(24-16)14(17(2,3)22)8-10-18(20,4)9-7-13/h14-16,21-22H,1,5-12H2,2-4H3/t14-,15?,16?,18+,19?,20?/m0/s1

Upstream product

• 401593-51-9 4-[(2S,5R)-2-[6-(tert-Butyl-diphenyl-silanyloxy)-3-methylene-hexyl]-5-(1-methoxymethoxy-1-methyl-ethyl)-2-methyl-cyclopent-(E)-ylidene]-2-(diethoxy-phosphoryl)-butyric acid ethyl ester 
• 401593-47-3 C₄₈H₇₂O₆SSi₂ 
• 401593-31-5 C₄₂H₆₈O₄Si₂ 
• 401593-49-5 2-[(2S,5R)-2-[6-(tert-Butyl-diphenyl-silanyloxy)-3-methylene-hexyl]-5-(1-methoxymethoxy-1-methyl-ethyl)-2-methyl-cyclopent-(E)-ylidene]-ethanol 
• 401593-32-6 2-(Diethoxy-phosphoryl)-4-[(2S,5R)-5-(1-methoxymethoxy-1-methyl-ethyl)-2-methyl-2-(3-methylene-6-oxo-hexyl)-cyclopent-(E)-ylidene]-butyric acid ethyl ester 
• 401593-28-0 {2-[(2R,5R)-2-Benzenesulfonylmethyl-5-(1-methoxymethoxy-1-methyl-ethyl)-2-methyl-cyclopent-(E)-ylidene]-ethoxy}-tert-butyl-dimethyl-silane 
• 401593-33-7 [(3aE,6E)-(3R,12aS)-3-(1-Methoxymethoxy-1-methyl-ethyl)-12a-methyl-10-methylene-1,2,3,5,8,9,10,11,12,12a-decahydro-cyclopentacycloundecen-6-yl]-methanol 
• 267245-06-7 stolonitriene 
• 401593-29-1 tert-butyl-(4-iodomethyl-pent-4-enyloxy)-diphenyl-silane 
• 401593-45-1 2-{(1R,3R)-2-[2-Hydroxy-eth-(E)-ylidene]-3-methyl-3-phenylsulfanylmethyl-cyclopentyl}-propan-2-ol 
• 152549-43-4 tert-butyl(4-methylpent-4-enyloxy)diphenylsilane 
• 131085-31-9 5-((tert-butyldiphenylsilyl)oxy)pentan-2-one 
• 1071-73-4 5-Hydroxy-2-pentanone 
• 401593-54-2 2-((E)-(1R,3R,12S,15S)-5-Hydroxymethyl-12-methyl-9-methylene-2-oxa-tricyclo[10.3.0.0^1,3]pentadec-5-en-15-yl)-propan-2-ol 

Downstream Products

• 112661-64-0 4-Bromo-benzoic acid (2R,4S,6S,12R)-4-acetoxymethyl-15-isopropenyl-12-methyl-9-methylene-5-oxa-tricyclo[10.3.0.0^4,6]pentadec-1⁽¹⁵⁾-en-2-yl ester 
• 116428-51-4 C₂₇H₃₅BrO₅ 
• 116428-52-5 4-Bromo-benzoic acid (1R,3R,5S,6R,12S,15S)-6-chloro-5-hydroxy-15-(1-hydroxy-1-methyl-ethyl)-12-methyl-9-methylene-2-oxa-tricyclo[10.3.0.0^1,3]pentadec-5-ylmethyl ester 

Relevant articles and documents

Total synthesis of marine diterpenoid stolonidiol

Marine dolabellane diterpenoid stolonidiol was synthesized from L-ascorbic acid. The method for this total synthesis involves formation of the bicyclo[2.2.1]heptane derivative using a diastereoselective sequential Michael reaction, formation of cyclopentane derivative by the retro-aldol reaction and construction of an 11-membered carbocyclic ring through the intramolecular Horner-Wadsworth-Emmons reaction.