401593-47-3

Upstream product

• 152549-43-4 tert-butyl(4-methylpent-4-enyloxy)diphenylsilane 
• 18162-48-6 tert-butyldimethylsilyl chloride 
• 131085-31-9 5-((tert-butyldiphenylsilyl)oxy)pentan-2-one 
• 1071-73-4 5-Hydroxy-2-pentanone 
• 401593-29-1 tert-butyl-(4-iodomethyl-pent-4-enyloxy)-diphenyl-silane 
• 401593-28-0 {2-[(2R,5R)-2-Benzenesulfonylmethyl-5-(1-methoxymethoxy-1-methyl-ethyl)-2-methyl-cyclopent-(E)-ylidene]-ethoxy}-tert-butyl-dimethyl-silane 
• 401593-45-1 2-{(1R,3R)-2-[2-Hydroxy-eth-(E)-ylidene]-3-methyl-3-phenylsulfanylmethyl-cyclopentyl}-propan-2-ol 

Downstream Products

• 401593-51-9 4-[(2S,5R)-2-[6-(tert-Butyl-diphenyl-silanyloxy)-3-methylene-hexyl]-5-(1-methoxymethoxy-1-methyl-ethyl)-2-methyl-cyclopent-(E)-ylidene]-2-(diethoxy-phosphoryl)-butyric acid ethyl ester 
• 401593-49-5 2-[(2S,5R)-2-[6-(tert-Butyl-diphenyl-silanyloxy)-3-methylene-hexyl]-5-(1-methoxymethoxy-1-methyl-ethyl)-2-methyl-cyclopent-(E)-ylidene]-ethanol 
• 112661-59-3 stolonidiol 
• 401593-31-5 C₄₂H₆₈O₄Si₂ 

Relevant academic research and scientific papers

Total synthesis of marine diterpenoid stolonidiol

Marine dolabellane diterpenoid stolonidiol was synthesized from L-ascorbic acid. The method for this total synthesis involves formation of the bicyclo[2.2.1]heptane derivative using a diastereoselective sequential Michael reaction, formation of cyclopentane derivative by the retro-aldol reaction and construction of an 11-membered carbocyclic ring through the intramolecular Horner-Wadsworth-Emmons reaction.