112756-05-5Relevant academic research and scientific papers
Microwave-enhanced, solvent-free synthesis of singly and doubly 13C-labelled trans-cinnamic acid at the α- and β-carbon positions
Ma, Guibin,Hayes, Sophia E.
, p. 895 - 901 (2004)
13C-labelled trans-cinnamic acid (3-phenyl-2-propenoic acid) has been synthesized in one step using benzaldehyde-carbonyl-13C and malonic acid-2-13C in the presence of ammonium acetate under microwave irradiation and solve
Use of the curtius rearrangement of acryloyl azides in the synthesis of 3,5-disubstituted pyridines: Mechanistic studies
Chuang, Ta-Hsien,Chen, Yu-Chi,Pola, Someshwar
supporting information; experimental part, p. 6625 - 6630 (2010/11/18)
A series of disubstituted pyridine derivatives was synthesized from the corresponding acryloyl azides by acetic acid-promoted cycloaddition. This represents a novel and convenient synthetic approach to the symmetric 3,5-disubstituted pyridines. The nature of the substituent on the double bond and the utilized solvent were found to be crucial to the yield of pyridines. The reactivity of the acid-promoted cycloaddition increases with the presence of aryl groups, such as phenyl and pyridinyl. We also explored the comprehensive mechanism by the acid-promoted cycloaddition of 13C-labeled cinnamoyl azide. The symmetric 3,5-disubstituted pyridines were synthesized from acryloyl azides by acetic acid-promoted trimolecular condensation.
Norlignan biosynthesis in Asparagus officinalis L.: The norlignan originates from two non-identical phenylpropane units
Suzuki,Umezawa,Shimada
, p. 3252 - 3257 (2007/10/03)
Little is known about the biosynthetic mechanism(s) of norlignans with C6-C5-C6 skeletons in spite of their important contributions to heartwood formation in conifers. To clarify the mechanism(s), we have established cell-
Dual p-coumaroyl CoA biosynthesis in Morus alba cell cultures
Hano, Yoshio,Shimazaki, Manabu,Nomura, Taro,Ueda, Shinichi
, p. 989 - 994 (2007/10/03)
Morus alba callus and cell suspension cultures specifically produce chalcomoracin (1) and kuwanon J (2) both originated from cinnamoylpolyketide intermediate. Administration of [2-13C]cinnamic acid N-acetylcysteamine thioester to the M. alba ce
