1129495-32-4Relevant academic research and scientific papers
One-pot synthesis of polyfluoroterphenyls via palladium-catalyzed Suzuki-Miyaura coupling of chlorobromobenzene and C-H bond functionalization of perfluoroarenes
Ma, Xiaowei,Gu, Ningning,Liu, Yan,Liu, Ping,Xie, Jianwei,Dai, Bin,Liu, Zhiyong
, p. 50 - 56 (2015)
An efficient tandem route for the synthesis of polyfluoroterphenyl derivatives has been developed. The target compounds were obtained in moderate to good yields by a Pd(OAc)2-catalyzed three-component coupling reaction involving palladium-catal
Palladium-Catalyzed Solid-State Polyfluoroarylation of Aryl Halides Using Mechanochemistry
Takahashi, Rikuro,Seo, Tamae,Kubota, Koji,Ito, Hajime
, p. 14803 - 14810 (2021/12/09)
The Suzuki–Miyaura cross-coupling between polyfluorinated arylboron nucleophiles and aryl halides enables the efficient construction of polyfluorinated structural motifs frequently found in organic materials and catalysts. A key challenge associated with
Palladium-catalyzed direct arylation of polyfluoroarene and facile synthesis of liquid crystal compounds
Ma, Xiaowei,Liu, Yan,Liu, Ping,Xie, Jianwei,Dai, Bin,Liu, Zhiyong
, p. 180 - 185 (2014/03/21)
A convenient approach has been developed to prepare polyfluorobiphenyl by Pd(OAc)2/PCy3-catalyzed direct arylation of polyfluoroarenes with aromatic halides in the presence of Cs2CO 3 as base and toluene as solvent. In most cases, the desired arylated products of aromatic bromides were obtained in good to excellent yield at 80°C, and aryl chlorides also gave modest to good yields of arylated products at 110°C. According to this efficient C - C bondforming method, polyfluorobiphenyl liquid crystal compounds were prepared by Pd-catalyzed direct arylation reactions of polyfluoroarenes with long alkyl chain substituted aryl bromides in 62-96% yield. Copyright
Synthesis of functionalized oligophenylenes and oligoarylenes bearing heteroaryl groups
Wallmann, Ivonne,Schnakenburg, Gregor,Luetzen, Arne
experimental part, p. 79 - 84 (2009/06/17)
Oligo-P-phenylenes have proven to be versatile building blocks for the generation of self-assembled nanoaggregates via vapour deposition on solid supports whose optical properties and morphologies can be influenced by the introduction of functional groups
