113033-32-2

Basic information

• Product Name: Pleurotin
• CAS NO: 113033-32-2
• Molecular Weight: 354.403
• Mol File: 113033-32-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pleurotin(CAS DataBase Reference)
• NIST Chemistry Reference: Pleurotin(113033-32-2)
• EPA Substance Registry System: Pleurotin(113033-32-2)

Safety Data

• Hazardous Substances Data: 113033-32-2(Hazardous Substances Data)

Upstream product

• 112946-29-9 Dihydropleurotin acid 
• 112946-40-4 rel-(3S,4S,4aS,7R,7aR,12bS,12cR)-2,3,4,4a,5,6,7,7a,8,12b-Decahydro-7-hydroxy-9,12-dimethoxy-3-methyl-12cH-4,12c-ethanoanthra<9,1-bc>oxepin 
• 112946-41-5 rel-(3S,4S,4aS,7aR,12bS,12cR)-2,3,4,4a,5,6,7,7a,8,12b-Decahydro-9,12-dimethoxy-3-methyl-7-oxo-12cH-4,12c-ethanoanthra<9,1-bc>oxepin 
• 112946-44-8 rel-(3S,4S,4aS,7R,7aS,12bS,12cR)-2,3,4,4a,5,6,7,7a,8,12b-Decahydro-9,12-dimethoxy-3-methyl-12cH-4,12c-ethanoanthra<9,1-bc>oxepin-7-carboxylic acid 
• 112946-43-7 rel-(3S,4S,4aS,7R,7aS,12bS,12cR)-2,3,4,4a,5,6,7,7a,8,12b-Decahydro-9,12-dimethoxy-3-methyl-12cH-4,12c-ethanoanthra<9,1-bc>oxepin-7-carboxaldehyde 
• 112946-42-6 rel-(3S,4S,4aS,7R,7aS,12bS,12cR)-7-Cyano-2,3,4,4a,5,6,7,7a,8,12b-decahydro-9,12-dimethoxy-3-methyl-12cH-4,12c-ethanoanthra<9,1-bc>oxepin 

Relevant articles and documents

Free-Radical Cyclizations: Application to the Total Synthesis of dl-Pleurotin and dl-Dihydropleurotin Acid

Total syntheses of the antitumor antibiotic pleurotin (1) and dihydropleurotin acid (2) are described.Early stages of the synthesis feature the construction of a trans perhydroindan substructure using a stereoselective free-radical cyclization, and the final stage of the synthesis involves the biomimetic conversion of dihydropleurotin acid (2) to pleurotin (1).