Journal of the American Chemical Society p. 7507 - 7519 (1989)
Update date:2022-09-26
Topics:
Hart, David J.
Huang, Horng-Chih
Krishnamurthy, Ram
Schwartz, Theresa
Total syntheses of the antitumor antibiotic pleurotin (1) and dihydropleurotin acid (2) are described.Early stages of the synthesis feature the construction of a trans perhydroindan substructure using a stereoselective free-radical cyclization, and the final stage of the synthesis involves the biomimetic conversion of dihydropleurotin acid (2) to pleurotin (1).
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