1131064-64-6Relevant articles and documents
The first peripherally masked thiol dendrimers: A facile and highly efficient functionalization strategy of polyester dendrimers via one-pot xanthate deprotection/thiol-acrylate Michael addition reactions
Auty, Sam E. R.,Andrén, Oliver,Malkoch, Michael,Rannard, Steven P.
, p. 6574 - 6577 (2014/06/10)
Introducing multiple reactive functional groups at the periphery of dendrimer materials presents considerable challenges if the functionality is able to self-react. An efficient and facile approach to introducing masked thiols at the surface of polyester dendrimers is presented. One-pot, deprotection/thiol-acrylate Michael addition from the xanthate-functional dendritic substrates (generation zero to two) has been achieved for the first time, with high efficiency demonstrated using three acrylates of varying chemistry and avoiding disulfide formation. This journal is the Partner Organisations 2014.
Synthesis, radiolabeling, and bio-imaging of high-generation polyester dendrimers
Parrott, Matthew C.,Benhabbour, S. Rahima,Saab, Chantal,Lemon, Jennifer A.,Parker, Shannon,et al.
supporting information; experimental part, p. 2906 - 2916 (2009/07/30)
A series of aliphatic polyester dendrons, generations 1 through 8, were prepared with a core p-toluenesulfonyl ethyl (TSe) ester as an easily removable protecting group that can be efficiently replaced with a variety of nucleophiles. Using amidation chemi
