113138-09-3

Basic information

• Product Name: Phosphorous acid, methyl bis(phenylmethyl) ester
• CAS NO: 113138-09-3
• Molecular Formula: C15H17O3P
• Molecular Weight: 276.272
• Mol File: 113138-09-3.mol

Chemical Properties

• CAS DataBase Reference: Phosphorous acid, methyl bis(phenylmethyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphorous acid, methyl bis(phenylmethyl) ester(113138-09-3)
• EPA Substance Registry System: Phosphorous acid, methyl bis(phenylmethyl) ester(113138-09-3)

Safety Data

• Hazardous Substances Data: 113138-09-3(Hazardous Substances Data)

Upstream product

• 173170-93-9 benzyl methyl N,N-diisopropylphosphoramidite 
• 100-51-6 benzyl alcohol 
• 67-56-1 methanol 
• 41662-50-4 dibenzyl chlorophosphite 

Downstream Products

• 166049-85-0 methylenebisphosphonic acid tribenzyl methyl ester 

Relevant articles and documents

Reactions of benzyl methyl substituted-benzyl phosphites with tert- butyl hypochlorite: 'Balanced TS' validating reactivity/selectivity principle

Reactions of a series of several benzyl methyl substituted-benzyl phosphites with tert-butyl hypochlorite were investigated. The reactions produced phosphates, isobutene, alkyl chlorides, and benzyl chlorides via phosphonium chlorides as intermediates. Fu

First Use of Benzyl Phosphites in the Michaelis-Arbuzov Reaction Synthesis of Mono-, Di-, and Triphosphate Analogs

Benzyl phosphites were used in the Michaelis-Arbuzov reaction.Special experimental conditions allowed preparation of a set of phosphonate analogs of mono-, di-, and triphosphate.Furthermore, regioselective mono-deprotection mades these molecules useful building blocks for the synthesis of analogs of polyphosphorylated compounds of biological interest (e.g. nucleotides), after removal of all phosphonate benzyl ester groups under very mild conditions and high yields.