A NEW EFFICIENT METHOD FOR THE GENERATION OF F-ALKYL KETONE METAL ENOLATES BY USING COPPER(II) BROMIDE-LITHIUM ALUMINIUM HYDRIDE REAGENT AND THEIR ALDOL REACTION WITH CARBONYL COMPOUNDS

Article abstract of DOI:10.1016/S0040-4039(00)96337-8

1-Substituted F-1-alkenyl phosphates, readily prepared from F-alkyl ketones end sodium diethyl phosphite, were treated with copper(II) bromide-lithium aluminium hydride reagent at -30 degC to generate in situ F-alkyl ketone aluminium enolates, which under