113138-63-9Relevant academic research and scientific papers
An unusual reaction of α-alkoxyphosphonium salts with Grignard reagents under an O2 atmosphere
Fujioka, Hiromichi,Goto, Akihiro,Otake, Kazuki,Kubo, Ozora,Sawama, Yoshinari,Maegawa, Tomohiro
, p. 9894 - 9896 (2011)
An unusual and novel reaction of α-alkoxyphosphonium salts, generated from O,O-acetals and Ph3P, with Grignard reagents under an O 2 atmosphere afforded alcohols in moderate to high yields. It was clarified by isotopic labelling experiments that the reaction proceeded via a novel radical pathway.
