113208-28-9

Upstream product

• 186581-53-3 diazomethane 
• 113331-54-7 (2R,3S,4R)-3-(tert-Butyl-dimethyl-silanyloxymethyl)-2-[2-(dimethyl-phenyl-silanyl)-4-oxo-butyl]-4-(tetrahydro-pyran-2-yloxy)-cyclopentanecarbaldehyde 
• 113208-25-6 4-[(1S,2S,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxymethyl-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-3-(dimethyl-phenyl-silanyl)-butyric acid methyl ester 
• 113208-27-8 (1S,2R,3aS,7aS)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(dimethyl-phenyl-silanyl)-2-(tetrahydro-pyran-2-yloxy)-2,3,3a,6,7,7a-hexahydro-1H-indene-5-carbaldehyde 
• 113208-26-7 4-[(1S,2S,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxymethyl-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-3-(dimethyl-phenyl-silanyl)-butan-1-ol 
• 113208-22-3 (E)-4-[(1R,2S,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-oxo-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-but-2-enoic acid methyl ester 
• 123536-33-4 (E)-4-[(1R,2S,3R,5S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxy-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-but-2-enoic acid methyl ester 
• 113428-17-4 (E)-4-[(1R,2S,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methylene-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-but-2-enoic acid methyl ester 
• 65025-95-8 (3aR,4S,5R,6aS)-4-({[dimethyl(2-methyl-2-propanyl)silyl]oxy}methyl)-5-(tetrahydro-2H-pyran-2-yloxy)hexahydro-2H-cyclopenta[b]furan-2-one 

Downstream Products

• 113208-30-3 5-[(1S,2R,3aS,7aS)-6-(Dimethyl-phenyl-silanyl)-1-hydroxymethyl-2-(tetrahydro-pyran-2-yloxy)-octahydro-inden-(5E)-ylidene]-pentanoic acid methyl ester 
• 113331-63-8 5-[(1R,2R,3aS,7aS)-6-(Dimethyl-phenyl-silanyl)-1-formyl-2-(tetrahydro-pyran-2-yloxy)-octahydro-inden-(5E)-ylidene]-pentanoic acid methyl ester 
• 113208-31-4 5-[(1R,2R,3aS,7aS)-6-(Dimethyl-phenyl-silanyl)-1-((E)-4-methyl-3-oxo-non-1-en-6-ynyl)-2-(tetrahydro-pyran-2-yloxy)-octahydro-inden-(5E)-ylidene]-pentanoic acid methyl ester 
• 113208-32-5 5-[(1R,2R,3aS,7aS)-6-(Dimethyl-phenyl-silanyl)-1-((E)-(R)-3-hydroxy-4-methyl-non-1-en-6-ynyl)-2-(tetrahydro-pyran-2-yloxy)-octahydro-inden-(5E)-ylidene]-pentanoic acid methyl ester 
• 113208-32-5 5-[(1R,2R,3aS,7aS)-6-(Dimethyl-phenyl-silanyl)-1-((E)-(S)-3-hydroxy-4-methyl-non-1-en-6-ynyl)-2-(tetrahydro-pyran-2-yloxy)-octahydro-inden-(5E)-ylidene]-pentanoic acid methyl ester 
• 113208-29-0 5-[(1S,2R,3aS,7aS)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(dimethyl-phenyl-silanyl)-2-(tetrahydro-pyran-2-yloxy)-octahydro-inden-(5E)-ylidene]-pentanoic acid methyl ester 
• 113331-69-4 5-[(1S,2R,3aS,7aS)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(dimethyl-phenyl-silanyl)-2-(tetrahydro-pyran-2-yloxy)-octahydro-inden-5-yl]-pentanoic acid methyl ester 
• 113208-29-0 5-[(1S,2R,3aS,7aS)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(dimethyl-phenyl-silanyl)-2-(tetrahydro-pyran-2-yloxy)-octahydro-inden-(5E)-ylidene]-pentanoic acid methyl ester 
• 113331-68-3 5-[(1S,2R,3aS,7aS)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(dimethyl-phenyl-silanyl)-2-(tetrahydro-pyran-2-yloxy)-2,3,3a,6,7,7a-hexahydro-1H-inden-5-yl]-pentanoic acid methyl ester 

Relevant academic research and scientific papers

STEREO- AND REGIOCONTROLLED CONSTRUCTION OF 3-ALKYL-CIS-BICYCLONON-3-ENE DERIVATIVES. AN EFFICIENT SYNTHESIS OF THE POTENT HOMOISOCARBACYCLIN ANALOG

The stereo- and regiocontrolled synthesis of the potent homoisocarbacyclin analog 2 has been achieved by a general strategy that hopefully will allow the synthesis of other 3-alkyl-cis-bicyclonon-3-ene derivatives.