113331-68-3

Upstream product

• 65025-95-8 (3aR,4S,5R,6aS)-4-({[dimethyl(2-methyl-2-propanyl)silyl]oxy}methyl)-5-(tetrahydro-2H-pyran-2-yloxy)hexahydro-2H-cyclopenta[b]furan-2-one 
• 113208-27-8 (1S,2R,3aS,7aS)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(dimethyl-phenyl-silanyl)-2-(tetrahydro-pyran-2-yloxy)-2,3,3a,6,7,7a-hexahydro-1H-indene-5-carbaldehyde 
• 113208-26-7 4-[(1S,2S,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxymethyl-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-3-(dimethyl-phenyl-silanyl)-butan-1-ol 
• 113208-22-3 (E)-4-[(1R,2S,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-oxo-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-but-2-enoic acid methyl ester 
• 123536-33-4 (E)-4-[(1R,2S,3R,5S)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-hydroxy-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-but-2-enoic acid methyl ester 
• 113428-17-4 (E)-4-[(1R,2S,3R)-2-(tert-Butyl-dimethyl-silanyloxymethyl)-5-methylene-3-(tetrahydro-pyran-2-yloxy)-cyclopentyl]-but-2-enoic acid methyl ester 
• 113208-28-9 (Z)-5-[(1S,2R,3aS,7aS)-1-(tert-Butyl-dimethyl-silanyloxymethyl)-6-(dimethyl-phenyl-silanyl)-2-(tetrahydro-pyran-2-yloxy)-2,3,3a,6,7,7a-hexahydro-1H-inden-5-yl]-pent-4-enoic acid methyl ester 

Relevant academic research and scientific papers

STEREO- AND REGIOCONTROLLED CONSTRUCTION OF 3-ALKYL-CIS-BICYCLONON-3-ENE DERIVATIVES. AN EFFICIENT SYNTHESIS OF THE POTENT HOMOISOCARBACYCLIN ANALOG

The stereo- and regiocontrolled synthesis of the potent homoisocarbacyclin analog 2 has been achieved by a general strategy that hopefully will allow the synthesis of other 3-alkyl-cis-bicyclonon-3-ene derivatives.