1133296-08-8Relevant academic research and scientific papers
Bronsted acid mediated nitrogenation of propargylic alcohols: An efficient approach to alkenyl nitriles
Huang, Xiaoqiang,Jiao, Ning
, p. 4324 - 4328 (2014)
A novel and efficient approach to alkenyl nitriles from readily available propargylic alcohols has been developed. This nitrogenation reaction is transition-metal-free and could be conducted under air at ambient temperature, which makes this protocol promising and practical. Moreover, NH4Br is disclosed as an efficient additive to promote the stereoselectivity of this reaction. the Partner Organisations 2014.
Reactivity of 3-silyloxy-1,4-enynes: Gold(III)-catalyzed regioselective nucleophilic substitution
Haug, Timm T.,Harschneck, Tobias,Duschek, Alexander,Lee, Chang-Uk,Binder, J?rg T.,Menz, Helge,Kirsch, Stefan F.
experimental part, p. 510 - 514 (2009/06/05)
Gold-catalyzed reactions of 3-silyloxy-1,4-enynes with alcohols afford primary, secondary, and tertiary pent-2-en-4-ynyl ethers in moderate to excellent yields. The substitution proceeds with high regioselectivity. An initial cyclization providing five-me
