113334-89-7

Basic information

• Product Name: Benzene, (3-methyl-2-nitro-1-butenyl)-
• CAS NO: 113334-89-7
• Molecular Formula: C11H13NO2
• Molecular Weight: 191.23
• Mol File: 113334-89-7.mol

Chemical Properties

• CAS DataBase Reference: Benzene, (3-methyl-2-nitro-1-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (3-methyl-2-nitro-1-butenyl)-(113334-89-7)
• EPA Substance Registry System: Benzene, (3-methyl-2-nitro-1-butenyl)-(113334-89-7)

Safety Data

• Hazardous Substances Data: 113334-89-7(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 906727-79-5 C₁₁H₁₅NO₃ 

Downstream Products

• 1301127-20-7 diethyl (S)-3-isopropyl-4-phenyl-4,5-dihydroisoxazole-5,5-dicarboxylate 2-oxide 

Relevant articles and documents

Dynamic kinetic asymmetric ring-opening/reductive amination sequence of racemic nitroepoxides with chiral amines: Enantioselective synthesis of chiral vicinal diamines

We report a highly diastereoselective synthesis of vicinal diamines by the treatment of nitroepoxides with primary amines and then a reducing agent. When using a chiral primary amine, racemic nitroepoxides are transformed into chiral diamines as a single enantiomers (>95:5 er) through a dynamic kinetic asymmetric transformation (DYKAT). The overall process is a one-pot procedure combining the exposure of nitroepoxides to chiral amines to afford diastereomeric mixtures of aminoimines and subsequent stereoselective imine reduction.