113340-14-0

Basic information

• Product Name: Carbamic acid, (4-hydroxy-2-cyclohepten-1-yl)-, phenylmethyl ester, cis-
• CAS NO: 113340-14-0
• Molecular Formula: C15H19NO3
• Molecular Weight: 261.321
• Mol File: 113340-14-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Carbamic acid, (4-hydroxy-2-cyclohepten-1-yl)-, phenylmethyl ester, cis-(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamic acid, (4-hydroxy-2-cyclohepten-1-yl)-, phenylmethyl ester, cis-(113340-14-0)
• EPA Substance Registry System: Carbamic acid, (4-hydroxy-2-cyclohepten-1-yl)-, phenylmethyl ester, cis-(113340-14-0)

Safety Data

• Hazardous Substances Data: 113340-14-0(Hazardous Substances Data)

Upstream product

• 113340-18-4 cis-4-aminocyclohept-2-enol 
• 501-53-1 benzyl chloroformate 
• 113340-06-0 8-oxa-9-azabicyclo<3.2.2>non-6-ene 
• 876938-53-3 Cyclohepta-1,3-diene 
• 3426-71-9 Benzyl N-hydroxycarbamate 
• 146309-04-8 6-Oxa-7-aza-bicyclo[3.2.2]non-8-ene-7-carboxylic acid benzyl ester 

Downstream Products

• 529-17-9 tropane 
• 146309-01-5 trop-6-ene 
• 113340-15-1 1-(amino)cyclohepta-2,4-diene 
• 18700-21-5 (+/-)-8-methyl-8-azabicyclo[3.2.1]octan-β-ol 
• 18700-21-5 (+/-)-8-methyl-8-azabicyclo[3.2.1]octan-α-ol 
• 169124-56-5 N-(benzyloxycarbonyl)-6β,7β-epoxy-8-azabicyclo<3.2.1>octane 
• 169219-73-2 N-(benzyloxycarbonyl)-6α,7α-epoxy-8-azabicyclo<3.2.1>octane 
• 169219-68-5 exo-6,7-epoxynortropane 
• 113340-08-2 cis-1-(amino)-4-acetoxycyclohept-2-ene 
• 182128-39-8 4-<(benzyloxycarbonyl)amino>cyclohept-2-enone 
• 113340-07-1 trans-1-(amino)-4-chlorocyclohept-2-ene 

Relevant articles and documents

Synthesis of Physoperuvine (8-Methyl-8-azabicyclooctan-1-ol), Norphysoperuvine and Dehydro-derivates

4-Aminocycloheptanones have been synthesized in high yield from cyclohepta-1,3-diene.These compounds exist mainly as the bicyclic tautomers (8-azabicyclooctan-1-ol derivatives; the title compounds) as shown by 13C NMR spectroscopy at low temperatur

A SIMPLE APPROACH TO NORTROPANE AND NORTROP-6-ENE DERIVATES

Intramolecular cyclisation of trans-1-(benzylamino)-4-chlorocycloheptane and hept-2-ene gives the corresponding 8-azabicyclo(3.2.1)octane (nortropane) and -oct-6-ene (nortrop-6-ene) derivatives respectively.Under appropriate conditions, cyclohept-1,3-diene is converted into nortropane in 75percent overall yield.