1133471-34-7Relevant academic research and scientific papers
Computational study of C-H insertion reactions with ethyl bromodiazoacetate
Bonge, Hanne Therse,Hansen, Tore
, p. 4355 - 4359 (2010)
A computational study of C-H insertion reactions between ethyl bromodiazoacetate and three different; substrates is presented. The mechanism, of the C-H insertion, is shown tobe substrate dependent; the reaction follows either a concerted mechanism, or a two-step mechanism in which, complete hydride transfer precedes C-C bond, formation.
Intermolecular C-H and Si-H insertion reactions with halodiazoacetates
Bonge, Hanne Therese,Hansen, Tore
experimental part, p. 91 - 96 (2009/06/24)
Ethyl halodiazoacetates react with a range of substrates in regioselective rhodium(II)-catalysed C-H and Si-H insertion reactions giving α-halocarbonyl products in up to 82% yield. The halodiazoacetates are a novel class of diazo compounds that can undergo intermolecular carbenoid C-H insertion reactions, thus broadening the synthetic utility of such reactions. Georg Thieme Verlag Stuttgart.
