113385-73-2

Usage

Uses

Used in UV-Cured Products Industry:
2,2'-(P-Tolyldiyl)bis(1-phenylethan-1-one) is used as a photoinitiator for the production of UV-cured inks, adhesives, and coatings. Its ability to initiate the polymerization process under UV light makes it a valuable component in the formulation of these products, ensuring rapid curing and high-quality results.
Used in Polymer Industry:
In the polymer industry, 2,2'-(P-Tolyldiyl)bis(1-phenylethan-1-one) is used as a stabilizer and crosslinking agent. Its presence in polymer formulations helps to improve the stability and performance of the final product, enhancing its durability and resistance to environmental factors.
Safety Considerations:
While PTPTB is known to have low toxicity and is considered to have low risk to human health and the environment, it is important to note that prolonged or repeated exposure may cause skin irritation or allergic reactions in some individuals. Therefore, proper handling and safety measures should be taken when working with 2,2'-(P-TOLYLAZANEDIYL)BIS(1-PHENYLETHANONE).

Upstream product

• 106-49-0 p-toluidine 
• 70-11-1 α-bromoacetophenone 
• 4831-18-9 N-phenacyl-p-toluidine 

Downstream Products

• 274690-29-8 1,2,6-triphenyl-4-(p-tolyl)-1,4-dihydropyrazine 
• 851-33-2 1,2,5-triphenyl-1H-pyrrole 
• 853-36-1 1-(4-methylphenyl)-2,5-diphenylpyrrole 
• 932023-01-3 5-(4-methylphenyl)-3,7-diphenyl-5,6-dihydro-4H-1,2,5-triazepine 
• 1026148-92-4 2-(4-methylphenyl)-4,10a-diphenyl-1,10a-dihydro-2H-pyrazino[2,1-b][1,3]benzoxazole 
• 65-85-0 benzoic acid 
• 79566-26-0 3,4-diphenyl-1-(p-tolyl)-1H-pyrrole 
• 123612-88-4 3,4-Diphenyl-1-p-tolyl-2,5-dihydro-1H-pyrrole 
• 274690-30-1 1-(4-trifluoromethylphenyl)-2,6-diphenyl-4-(p-tolyl)-1,4-dihydropyrazine 
• 113385-74-3 2,6-diphenyl-1,4-bis(p-tolyl)-1,4-dihydropyrazine 
• 113385-76-5 3,6-diphenyl-1,2-di-p-tolyl-1,2-dihydropyrazine 
• 1446221-33-5 2,6-bisphenyl-4-(4-methylphenyl)-4H-1,4-oxazine 
• 26463-62-7 1,4-diphenyl-2-(p-tolylamino)but-2-ene-1,4-dione 
• 36004-54-3 phenyl(3-phenyl-1H-indol-2-yl)methanone 

Relevant academic research and scientific papers

Ultrasound-mediated synthesis of N,N-bis(phenacyl)aniline under solvent-free conditions

An efficient method for the synthesis of N,N-bis(phenacyl)anilines was developed via smooth condensation of anilines with α-bromoacetophenones in the presence of sodium carbonate as acid acceptor and polyethylene glycol 400 (PEG 400) as catalyst at room t

Synthesis and photochemical properties of 2,4,6,-triaryl-4h-1,4-oxazines

A series of 2,4,6-triaryl-4H-1,4-oxazines was synthesized, and their photochemical properties were studied. The 2,4,6-triaryl-4H-1,4-oxazines underwent photoreaction to N-(1-methoxy-2-oxo-2-arylethyl)-N-arylformamides determined by 1H NMR, 13C NMR, MS, and single crystal X-ray diffraction analyses.

Synthesis of 4H-1,4-oxazines as transthyretin amyloid fibril inhibitors

4H-1,4-oxazines were designed as transthyretin (TTR) amyloid fibril inhibitors based on an analysis of the interactions between known small molecule inhibitors and TTR by molecular docking. A series of 2,4,6-triaryl-4H-1,4- oxazines was synthesized by the

Synthesis of oxathiane and morpholine from acyclic precursors: A modified Mitsunobu reaction

Synthesis of a set of isomeric 2,4,6-triarylmorpholines and 2,6-diaryloxathianes from the corresponding 1,5-diols has been described. The method provides an efficient route to six-membered heterocycles from acyclic diols and is found to be better than Mitsunobu procedure in yield and waste management. In a related study, the ring contraction of pyranone to two isomeric cyclopentenone derivatives through Nazarov reaction has been noticed.

Synthesis of novel 3,5,7-triaryl-5,6-dihydro-4H-1,2,5-triazepines

(Chemical Equation Presented) Several hitherto unknown 3,5,7-triaryl-5,6- dihydro-4H-1,2,5-triazepines have been synthesised by cyclocondensation of N,N-bis(phenacyl)anilines with hydrazine hydrate in ethanol or ethyleneglycol under reflux condition. Incr

Study on photochromism of diarylethenes with a 2,5-dihydropyrrole bridging unit: A convenient preparation of 3,4-diarylpyrroles from 3,4-diaryl-2,5- dihydropyrroles

Symmetric and nonsymmetric diarylethenes with a 2,5-dihydropyrrole bridging unit have been prepared, and the photochromic properties are investigated. Both symmetric and nonsymmetric diarylethenes with 2,5-dihydropyrrole bridging units undergo reversible ring-opening and ring-closing photoisomerization reactions in nonpolar solvents with UV/vis light, and some of them exhibit good fatigue resistance and no marked degradation detected after 10 cycles via an on/off switch. In polar solvents, however, photochromic diarylethenes with 2,5-dihydropyrrole bridging units produce 3,4-diarylpyrrole derivatives instead of the ring-closing isomer of diarylethenes with UV light irradiation. A class of N-substituted 3,4-diphenylethenes with 2,5-dihydropyrrole bridging units were prepared and used as templates to investigate the conversion reactions. The mechanism of photoconversion of 3,4-diaryl-2,5-dihydropyrroles to 3,4-diarylpyrroles was explored as well.

Photochemistry of N-heterocycles. 7: Light induced reductive ring contractions of sixmembered cyclic iminium ions

Photochemically induced reductive ring contractions, previously observed for 2,5-dihydro-1,2,4-triazines, have also been verified for 1,4-dihydropyrimidines 2a,b, the dihydro-1,2,4,5-tetrazine 9, and dihydro-1,3,5-triazines 11a,b giving rise to fivemembered fully unsaturated heterocycles (pyrroles 4a,b, imidazoles 13a,b, and triazole 10, respectively). The 1,4-dihydropyrazines 15a-j tend to decompose in acidified 2-propanol in the dark, but on irradiation they also undergo reductive ring contraction furnishing solely the 1,2,5-triarylpyrroles 16a-d rather than the (a priori also possible) isomeric 1,3,4-triarylpyrroles 17a-d. In contrast, the 3,6-diphenylpyrid-azine 18 gives the 4-isopropyl-analogue 19 in low yield upon irradiation in hydrogen chloride saturated 2-propanol. Wiley-VCH Verlag GmbH, 2000.

Preparation of Stable 1,4-Dihydropyrazines

The N-phenacylarylamine (4) gives the N,N-diphenacyl derivative (5) on treatment with phenacyl bromine under phase-transfer catalysis conditions.Condensation of (5) with an arylamine results in the formation of the thermally stable 1,4-diaryl-3,5-diphenyl