113402-77-0

Usage

Uses

Used in Pharmaceutical and Agrochemical Industries:
3-Chloro-2-iodo-1,1,1-trifluoropropane is used as a chemical intermediate for the synthesis of pharmaceuticals and agrochemicals. Its unique structure and reactivity enable the production of a wide range of organic compounds with diverse applications in these industries.
Used in Fluorinated Polymer Production:
3-CHLORO-2-IODO-1,1,1-TRIFLUOROPROPANE is utilized in the production of fluorinated polymers, which are known for their exceptional properties such as heat resistance, chemical resistance, and non-stick characteristics. These polymers find applications in various industries, including automotive, aerospace, and electronics.
Used in Electronics and Semiconductor Industries:
3-Chloro-2-iodo-1,1,1-trifluoropropane is employed in the electronics and semiconductor industries for various applications, such as the fabrication of electronic devices and components. Its unique properties make it suitable for use in these high-tech industries.
However, due to its potential toxicity and environmental impact, the handling and use of 3-chloro-2-iodo-1,1,1-trifluoropropane should be carefully regulated and monitored to ensure safety and minimize adverse effects.

InChI:InChI=1/C3H3ClF3I/c4-1-2(8)3(5,6)7/h2H,1H2

Upstream product

• 677-21-4 1,1,1-trifluoropropylene 
• 1514-82-5 2-bromo-3,3,3-trifluoropropene 

Downstream Products

• 2730-62-3 2-chloro-1,1,1-trifluoropropene 
• 2730-43-0 1-chloro-3,3,3-trifluoropropene 
• 107070-09-7 2-iodo-3,3,3-trifluoropropene 

Relevant academic research and scientific papers

PROCESS FOR 1-CHLORO-3,3,3-TRIFLUOROPROPENE FROM TRIFLUOROPROPENE

The present invention provides routes for making 1-chloro-3,3,3-trifluoropropene (HCFO-1233zd) from commercially available raw materials. More specifically, this invention provides several routes for forming HCFO-1233zd from 3,3,3-trifluoropropene (FC-1234zf).

Reactions of gaseous, halogenated propene radical cations with ammonia: A study of the mechanism by Fourier transform ion cyclotron resonance

The gas-phase ion-molecule reactions of the radical cations of 2-chloropropene (1+.), 2-bromopropene (2+.), and 2-iodopropene (3+.), as well as of the corresponding three 3,3,3-trifluoropropenes (4+.- 6+.) with ammonia have been studied by FT-ICR mass spectrometry complemented by ab initio calculations of the reaction thermochemistry. In all cases a deprotonation of the 2-halopropene radical cations by ammonia is distinctly exothermic. In spite of this, the substitution of the halo substituent by NH3 is the main reaction pathway for 1+. and 2+. and is still competing for the slowly reacting iodo derivative 3+.. In the latter case deprotonation generates not only NH(4/+), but also the proton-bridged dimer [H3N·· H+··NH3]. These effects prove that the first addition step of the substitution by an addition-elimination mechanism of the haloalkene radical cations can compete effectively with exothermic deprotonation and occurs without noticeable activation energy. In fact it appears likely that the deprotonation of the unsaturated radical cations proceeds also by an addition-elimination process. The calculation of the reaction enthalpy shows that addition of NH3 to the ionized 3,3,3-trifluoro-2-halopropenes 4+.-6+. is especially exothermic. Experimentally this effect is not only reflected in the increased reaction efficiency of the substitution product, even in the case of the iodo derivative 6+., but also in competing fragmentations of the strongly excited distonic intermediates generated by the addition step. This corroborates the postulate that the variation of the rate constants with the substituents, which is observed for the reactions of ionized haloalkenes with ammonia, is caused by the excess energy released in the initial addition step.