113427-15-9

Basic information

• Product Name: Propanedioic acid, [4-(acetyloxy)-2-cyclohexen-1-yl]-2-propenyl-, dimethyl ester, trans-
• CAS NO: 113427-15-9
• Molecular Formula: C16H22O6
• Molecular Weight: 310.347
• Mol File: 113427-15-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Propanedioic acid, [4-(acetyloxy)-2-cyclohexen-1-yl]-2-propenyl-, dimethyl ester, trans-(CAS DataBase Reference)
• NIST Chemistry Reference: Propanedioic acid, [4-(acetyloxy)-2-cyclohexen-1-yl]-2-propenyl-, dimethyl ester, trans-(113427-15-9)
• EPA Substance Registry System: Propanedioic acid, [4-(acetyloxy)-2-cyclohexen-1-yl]-2-propenyl-, dimethyl ester, trans-(113427-15-9)

Safety Data

• Hazardous Substances Data: 113427-15-9(Hazardous Substances Data)

Upstream product

• 108-59-8 malonic acid dimethyl ester 
• 40637-56-7 dimethyl allylmalonate 
• 82736-39-8 cis-1-acetoxy-4-chlorocyclohex-2-ene 

Downstream Products

• 136569-37-4 2-((E)-4-Acetoxy-but-2-enyl)-2-[(1S,4S)-4-(1,1-bis-methoxycarbonyl-but-3-enyl)-cyclohex-2-enyl]-malonic acid dimethyl ester 
• 136569-44-3 dimethyl -2-cyclohexenyl>allylmalonate 

Relevant articles and documents

Rhodium(I)-Ctalyzed 'Metallo-Ene' Cyclizations/β-Eliminations

Octadienyl carbonates 5 provide cyclic 1,4-dienes 6 when treated with RhI complexes (1-10 mol-percent) at 80 deg C.Similar cyclization of cyclohexenyl acetate 8 affords cis-fused hexahydroindene 9.Analogues ring closures of nonadiene carbonate 10 yield preferably the cis-divinylpyrrolidine 11 with RhI catalysis but the trans-isomer 12 when catalyzed by Pd0.Azaoctadienyl carbonate 5a undergoes elimination with (5 mol-percent, 80 deg C) in MeCN giving acyclic triene 7.

134. Catalytic Intramolecular Palladium-Ene Reactions

Pd(dba)2/PPh3- or Pd(PPh3)4-catalyzed cyclizations of acetoxy-dienes 2 -> 3 and 10 -> 11 gave 1-vinyl-2-methylidene-substituted cyclopentanes and cyclohexanes in high yield, consistent with a palladium-ene/β-elimination mechani