136569-44-3Relevant academic research and scientific papers
Direct Syntheses of Polyfused Ring Systems by Intramolecular Tandem Palladium-Ene/Heck Insertion Reactions
Oppolzer, Wolfgang,DeVita, Robert J.
, p. 6256 - 6257 (1991)
The Pd(0)-catalyzed polycyclizations 1 -> 3 + 4, 5 -> 9 and 6 -> 10 are described.The stereospecifity of these transformations is ascribed to an intramolecular suprafacial "palladium-ene" process followed by one to two "Heck-insertions" proceeding with re
