1134435-73-6Relevant articles and documents
Chemoselective Organoclick-Click Sequence
Belkheira, Mokhtaria,El Abed, Douniazad,Pons, Jean-Marc,Bressy, Cyril
, p. 4254 - 4262 (2018/11/23)
A highly chemoselective bis-triazole synthesis based on a sequence organocatalyzed click reaction/copper-catalyzed click reaction is described in this paper. A range of bis-azides react with various ketones using proline catalysis through the aryl azide moiety while the alkyl azide one remains available for a metal-catalyzed triazole synthesis.
Chemoselective reduction of azides catalyzed by molybdenum xanthate by using phenylsilane as the hydride source
Maddani, Mahagundappa R.,Moorthy, Saravana K.,Prabhu, Kandikere R.
supporting information; experimental part, p. 329 - 333 (2010/03/01)
A chemoselective, neutral, and efficient strategy for the reduction of azides to corresponding amines catalyzed by dioxobis(N,N,-diethyldithiocarbamato) molybdenum complex (1, MoO2[S2CNEt2]2) in the presence of phenylsilane is discovered. This chemoselective reduction strategy tolerates a variety of reducible functional groups.
Benzylic Newman-Kwart rearrangement of O-azidobenzyl thiocarbamates triggered by phosphines: pseudopericyclic [1,3] shifts via uncoupled concerted mechanisms
Alajarin, Mateo,Marin-Luna, Marta,Ortin, Maria-Mar,Sanchez-Andrada, Pilar,Vidal, Angel
experimental part, p. 2579 - 2590 (2009/08/07)
A series of O-(o- and p-azido)benzyl thiocarbamates smoothly rearranged in the course of Staudinger imination reactions with tertiary phosphines, giving rise to the respective S-(o- and p-phosphinimino)benzyl thiocarbamates as a result of an oxygen to sul
