113489-84-2

Basic information

• Product Name: (2'R,3'S,4R,5S)-3-(3'-hydroxy-2'-methyl-1'-oxo-5'-pentenyl)-4-methyl-5-phenyl-2-oxazolidone
• Synonyms: (2'R,3'S,4R,5S)-3-(3'-hydroxy-2'-methyl-1'-oxo-5'-pentenyl)-4-methyl-5-phenyl-2-oxazolidone
• CAS NO: 113489-84-2
• Molecular Weight: 289.331
• Mol File: 113489-84-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2'R,3'S,4R,5S)-3-(3'-hydroxy-2'-methyl-1'-oxo-5'-pentenyl)-4-methyl-5-phenyl-2-oxazolidone(CAS DataBase Reference)
• NIST Chemistry Reference: (2'R,3'S,4R,5S)-3-(3'-hydroxy-2'-methyl-1'-oxo-5'-pentenyl)-4-methyl-5-phenyl-2-oxazolidone(113489-84-2)
• EPA Substance Registry System: (2'R,3'S,4R,5S)-3-(3'-hydroxy-2'-methyl-1'-oxo-5'-pentenyl)-4-methyl-5-phenyl-2-oxazolidone(113489-84-2)

Safety Data

• Hazardous Substances Data: 113489-84-2(Hazardous Substances Data)

Upstream product

• 77877-20-4 (4R,5S)-4-methyl-5-phenyl-3-propionyloxazolidin-2-one 
• 107-02-8 acrolein 

Downstream Products

• 849482-36-6 Benzoic acid (R)-1-[(R)-1-methyl-2-((4R,5S)-4-methyl-2-oxo-5-phenyl-oxazolidin-3-yl)-2-oxo-ethyl]-allyl ester 
• 113490-00-9 (2R,2'R,6'S)-7'-<(tert-butyldimethylsilyl)oxy>-2',6'-dimethyl-1'-heptyl 2-methoxy-2-phenyl-3,3,3-trifluoropropanoate 
• 92934-94-6 (2R,6S)-7-<(tert-butyldimethylsilyl)oxy>-2,6-dimethyl-1-heptyl p-toluenesulfonate 
• 113490-20-3 (3R,7R,11S,15R,18R,22S,26R,30R)-1,32-bis<(tert-butyldiphenylsilyl)oxy>-3,7,11,15,18,22,26,30-octamethylduotricontane 
• 104423-53-2 (2R,6R,8R^*,10S,14R)-1-<(tert-butyldimethylsilyl)oxy>-16-<(tert-butyldiphenylsilyl)oxy>-2,6,10,14-tetramethyl-8-hexadecyl phenyl sulfone 
• 113490-04-3 (2S,6R,10S,14R)-1-<(tert-butyldimethylsilyl)oxy>-16-<(2'-methoxyethoxy)methoxy>-9-(phenylsulfonyl)-2,6,10,14-tetramethylhexadecane 
• 113490-19-0 (2R,6S,10R,14R)-16-<(tert-butyldiphenylsilyl)oxy>-2,6,10,14-tetramethyl-1-hexadecyl methanesulfonate 
• 113490-17-8 (2R,6S,10R,14R)-1-<(tert-butyldimethylsilyl)oxy>-16-<(tert-butyldiphenylsilyl)oxy>-2,6,10,14-tetramethylhexadecane 

Relevant articles and documents

Synthesis of the C6-C14 Fragment of Euphosalicin

The synthesis of the C6-C14 fragment of euphosalicin, a highly oxygenated modified jatrophane diterpene, is described. Key steps in the preparation of this versatile intermediate are an Ireland-Claisen rearrangement and a Shibasaki direct asymmetric aldol reaction.

1,4- and 1,5-Stereoselection by Sequential Aldol Addition to α,β-Unsaturated Aldehydes Followed by Claisen Rearrangement. Application to Total Synthesis of the Vitamin E Side Chain and the Archaebacterial C40 Diol

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