113501-09-0

Basic information

• Product Name: (1S,2S)-2-Chloro-1-phenyl-but-3-en-1-ol
• CAS NO: 113501-09-0
• Molecular Weight: 182.65
• Mol File: 113501-09-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: (1S,2S)-2-Chloro-1-phenyl-but-3-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S)-2-Chloro-1-phenyl-but-3-en-1-ol(113501-09-0)
• EPA Substance Registry System: (1S,2S)-2-Chloro-1-phenyl-but-3-en-1-ol(113501-09-0)

Safety Data

• Hazardous Substances Data: 113501-09-0(Hazardous Substances Data)

Upstream product

• 158813-39-9 2-(Z-3-chloroprop-2-enyl)-4,4,5,5-tetramethyl-1,2,3-dioxaborolane 
• 100-52-7 benzaldehyde 
• 18083-15-3 3-chloroallyltrichlorosilane 
• 542-75-6 E/Z-1,3-Dichloropropene 
• 107-05-1 3-chloroprop-1-ene 
• 88086-59-3 1-chloro-3-iodoprop-1(Z)-ene 

Downstream Products

• 182210-51-1 cis-(1R,2S)-1,2-epoxy-1-phenyl-3-butene 
• 182210-57-7 cis-(1S,2R)-1,2-epoxy-1-phenyl-3-butene 
• 21699-63-8 cis-2-phenyl-3-ethenyl oxirane 
• 16939-57-4 (E)-buta-1,3-dienylbenzene 
• 21699-64-9 trans-2-phenyl-3-ethenyl oxirane 

Relevant articles and documents

Either γ-syn- Or γ-anti-selective palladium-catalysed carbonyl allylation by mixed (E)- and (Z)-l,3-dichloropropene with tin(II) halides

Palladium-catalysed carbonyl allylations by mixed (E)- and (Z)-1,3-dichloropropene with SnI2-Bu4NI and SnCl2 diastereoselectively produce syn and anti 1-substituted 2-chlorobut-3-en-1-ols, respectively. These are transform

Synthesis of γ-functionalized allyltrichlorosilanes and their application in the asymmetric allylation of aldehydes

Isomerically pure trans-and cis-γ-bromoallyltrichlorosilanes 4 and 5 have been synthesized and shown to react with aromatic aldehydes 1 in the presence of Lewis-basic catalysts (e.g., DMF) to produce the corresponding anti-and syn-allylbromohydrins 8 and 9, respectively, as single diastereoisomers. With BINAPO 25 as a chiral catalyst, promising enantioselectivity (≤50% ee) has been attained.

Indium-mediated reaction of 1,3-dichloro- and 1,3-dibromopropenes with carbonyl compounds. Generation of novel 3,3-diindiopropene

Indium-mediated reaction of 1,3-dichloropropene with aldehyde gave syn-chlorohydrin predominantly. A similar reaction of 1,3-dibromopropene gave vinyloxirane and homoallyl alcohol; the former is formed from γ-bromoallylindium via the corresponding bromohydrin, and the latter is considered to be derived from a unique allylic diindium reagent, 3,3-diindiopropene.