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113543-52-5

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113543-52-5 Usage

Description

(S)-Benzyl 2-azido-2-phenylethanoate, a member of the benzoate class of compounds, is a chemical compound with the molecular formula C16H15N3O2. It is characterized by the presence of a benzyl group attached to a 2-azido-2-phenylethanoate moiety. (S)-BENZYL 2-AZIDO-2-PHENYLETHANOATE is known for its potential applications in organic synthesis, particularly in azide chemistry, and is also of interest for its potential biological activities.

Uses

Used in Organic Synthesis:
(S)-Benzyl 2-azido-2-phenylethanoate is used as a reagent in the synthesis of various organic molecules, particularly in the field of azide chemistry. Its azide functional group makes it a versatile intermediate for the preparation of azide-containing compounds, which are valuable in the synthesis of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Pharmaceutical Industry:
(S)-Benzyl 2-azido-2-phenylethanoate is used as a key intermediate in the synthesis of pharmaceutical compounds. Its unique structure and reactivity allow for the development of novel drug candidates with potential therapeutic applications.
Used in Agrochemical Industry:
In the agrochemical industry, (S)-benzyl 2-azido-2-phenylethanoate is used as a building block for the synthesis of agrochemicals, such as pesticides and herbicides. Its azide functionality can be utilized to create new molecules with improved efficacy and selectivity.
Used in Specialty Chemicals:
(S)-Benzyl 2-azido-2-phenylethanoate is also used in the synthesis of specialty chemicals, including dyes, polymers, and materials with unique properties. Its versatility as a synthetic intermediate allows for the development of innovative products with specific applications in various industries.
Used in Research and Development:
Due to its potential biological activities and unique chemical properties, (S)-benzyl 2-azido-2-phenylethanoate is used as a research tool in academic and industrial laboratories. It serves as a starting material for the exploration of new chemical reactions and the development of novel synthetic methodologies.

Check Digit Verification of cas no

The CAS Registry Mumber 113543-52-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,1,3,5,4 and 3 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 113543-52:
(8*1)+(7*1)+(6*3)+(5*5)+(4*4)+(3*3)+(2*5)+(1*2)=95
95 % 10 = 5
So 113543-52-5 is a valid CAS Registry Number.

113543-52-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name (S)-Benzyl 2-azido-2-phenylethanoate

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
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More Details:113543-52-5 SDS

113543-52-5Downstream Products

113543-52-5Relevant articles and documents

Boron-Catalyzed Azide Insertion of α-Aryl α-Diazoesters

San, Htet Htet,Wang, Chun-Ying,Zeng, Hai-Peng,Fu, Shi-Tao,Tang, Xiang-Ying,Jiang, Min

, p. 4478 - 4485 (2019/05/01)

A challenging metal-free azide insertion of α-aryl α-diazoesters in the presence of B(C6F5)3 (5 mol %) was developed for the first time. The reaction features an easy operation, wide substrate scope, and mild conditions an

The asymmetric synthesis of α-amino acids. Electrophilic azidation of chiral imide enolates, a practical approach to the synthesis of (R)- and (S)-α-azido carboxylic acids

Evans, David A.,Britton, Thomas C.,Ellman, Jonathan A.,Dorow, Roberta L.

, p. 4011 - 4030 (2007/10/02)

Two complementary approaches to the asymmetric synthesis of α-amino acids have been achieved. In the initially investigated reaction sequence, the diastereoselective bromination of the illustrated boron enolate with N-bromosuccinimide was followed by stereospecific azide displacement by tetramethylguanidinium azide. The resulting α-azido carboximides may be readily purified to high diastereomeric purity by chromatography on silica. equation presented In the second reaction sequence, the illustrated potassium enolate was treated with 2,4,6-triisopropylbenzenesulfonyl azide, and the intermediate sulfonyl triazene was decomposed through an acetic acid quench to give the α-azido carboximide. The diastereoselection of the reaction as a function of R is as follows: R = Me, CH2Ph, 97:3; R = CHMe2, 98:2; R = CMe3, >99:1; R = Ph, 91:9. The important parameters of this azidation process were evaluated, and experiments were conducted to help elucidate the mechanism of the reaction. equation presented The α-azido carboximide products have been shown to be versatile α-amino acid synthons that may be readily converted to α-amino acids as well as to N-protected α-amino acid derivatives. The racemization-free removal of the chiral auxiliary was achieved in high yield both by saponification and transesterification, either before or after reduction and acylation of the azide functionality.

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