113566-67-9

Basic information

• Product Name: 4,6-O-benzylidene-α-D-glucopyranose
• Synonyms: 4,6-O-benzylidene-α-D-glucopyranose
• CAS NO: 113566-67-9
• Molecular Weight: 268.266
• Mol File: 113566-67-9.mol
• Article Data: 40

Chemical Properties

• CAS DataBase Reference: 4,6-O-benzylidene-α-D-glucopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 4,6-O-benzylidene-α-D-glucopyranose(113566-67-9)
• EPA Substance Registry System: 4,6-O-benzylidene-α-D-glucopyranose(113566-67-9)

Safety Data

• Hazardous Substances Data: 113566-67-9(Hazardous Substances Data)

Upstream product

• 2280-44-6 D-Glucose 
• 100-52-7 benzaldehyde 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 492-62-6 alpha-D-glucopyranose 
• 50-99-7 D-glucose 
• 59-23-4 D-Galactose 
• 1269490-06-3 N,O-dimethyl-N-(4,6-O-benzylidene-β-D-glucopyranosyl)hydroxylamine 
• 10257-28-0 D-Galactose 
• 530-26-7 D-Mannose 
• 572-09-8 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl bromide 
• 604-69-3 β-D-glucose pentaacetate 
• 113533-74-7 (2R,4aR,7R,8R,8aS)-6-Pent-4-enyloxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 492-61-5 β-D-glucose 

Downstream Products

• 116237-14-0 2,4-O-Benzylidene-3-formyl-D-erythrose 
• 784179-19-7 benzyl 4,6-O-benzylidene-2,3-tri-O-benzyl-α,β-D-glucopyranoside 

Relevant articles and documents

Acetolysis of 2,4-O-benzylidene-L-ribo-hex-5-enitol derivative

Acetolysis of (Z)-1,3-di-O-acetyl-2,4-O-benzylidene-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-L-ribo-hex-5-enitol afforded, besides 2-C--3,4,6-tri-O-acetyl-2-deoxy-β-D-allo- and -gluco-hexopyranosylbenzene, (E)-1,2,3,4-tetra-O-acetyl-5,6-dideoxy-6-C-(2,4-dichlorophenyl)-D-lyxo- and -L-ribo-hex-5-enitol as main products.The rate of this reaction as well as the ratio of the products depends on the chirality of C-3.This was confirmed by acetolysis of the corresponding L-erythro-pent-4-enitol derivative.

An Improved, Versatile, and Easily Scalable Synthesis of Sphingomyelins: Application to Stable Isotope Labeling

With a view to make conveniently labeled mass spectrometry standards available, a set of deuterated sphingomyelins were prepared by a new expedient, flexible, robust, scalable, and high-yielding synthetic scheme starting from 2-azido-3- O -benzoylsphingos

Oligosaccharide compound and its manufacture and its intermediate

The purpose of the present invention is to provide an oligosaccharide with high versatility that can produce a protected sulfate oligosaccharide that can become a manufacturing intermediate of polysulfated hyaluronic acid, and to provide a manufacturing method therefor and an intermediate thereof. Position 2 amino groups in glucosamine, galactosamine, and the like can react with saccharide receptors having an electron attracting group such as glucuronic acid and protected sulfate groups, by using a saccharide donor protected by a specific protective group.