113709-42-5

Usage

Classification

Azetidinone derivative

Molecular structure

Contains a four-membered ring with a nitrogen atom

Isomer form

Trans geometric isomer

Molecular groups

Methyl group at the 4th carbon position, octyl group at the 3rd carbon position, phenylmethyl group at the 1st carbon position

Properties

Distinct chemical properties

Potential applications

Pharmaceuticals, agriculture, material science

Upstream product

• 96201-10-4 benzyl(tert-butyldimethylsilyl)amine 
• 507444-65-7 methyl 3-(benzylamino)butanoate 
• 14856-79-2 N-benzyl(trimethylsilyl)amine 
• 629-27-6 1-Iodooctane 
• 113709-50-5 Lithium N-benzyl-N-(trimethylsilyl)amide 
• 113709-36-7 methyl 3-(benzylamino)-2-octylbutanoate 
• 113709-36-7 methyl 3-(benzylamino)-2-octylbutanoate 

Relevant academic research and scientific papers

LITHIUM N-BENZYLTRIMETHYLSILYLAMIDE (LSA): A NEW REAGENT FOR CONJUGATE ADDITION - ENOLATE TRAPPING REACTIONS

Lithium N-benzyltrimethylsilylamide (LSA) adds to crotonates in a 1,4-manner, though the reaction of ordinary lithium amides with α,β-unsaturated carbonyl compounds is accompanied with a 1,2-addition and hydrogen abstraction at the γ-position.The conjugat

Stereoselective α-Alkylation of α,β-Unsaturated Esters Utilizing Conjugate Addition of Nitrogen Nucleophiles (R2NLi)

Treatment of α,β-unsaturated esters (1) with lithium amides i2 and LiN(CH2Ph)SiMe3> followed by alkylation and elimination of the amino groups produced trisubstituted enoates (2) with high stereoselectivity.