113791-99-4Relevant articles and documents
[3 + 2] Cycloadditions and protonation by alcohols of photochemically generated nitrile ylides from 2H-Azirines. Formation and reactivities of azaallenium cations
Albrecht, Evelyn,Mattay, Jochen,Steenken, Steen
, p. 11605 - 11610 (2007/10/03)
On photolysis of 2H-phenylazirines in acetonitrile or alcohol solution with 248 nm laser light, phenylnitrile ylides are formed by heterolytic cleavage of the C-C bond of the azirines. The absorption spectra of the ylides are characterized by two strong b