113791-99-4Relevant academic research and scientific papers
[3 + 2] Cycloadditions and protonation by alcohols of photochemically generated nitrile ylides from 2H-Azirines. Formation and reactivities of azaallenium cations
Albrecht, Evelyn,Mattay, Jochen,Steenken, Steen
, p. 11605 - 11610 (2007/10/03)
On photolysis of 2H-phenylazirines in acetonitrile or alcohol solution with 248 nm laser light, phenylnitrile ylides are formed by heterolytic cleavage of the C-C bond of the azirines. The absorption spectra of the ylides are characterized by two strong b
OXIDATION OF N-BENZYLIDENEBENZYLAMINE BY OXYGEN THROUGH THE FORMATION OF A CARBANION
Grigoryan, G. S.,Tovmasyan, V. S.,Malkhasyan, A. Ts.,Martirosyan, G. T.,Beletskaya, I. P.
, p. 1043 - 1046 (2007/10/02)
A study was carried out on the oxidation of the methylene group of N-benzylidenebenzylamine through the formation of a carbanion.The conditions were found for a combined oxidation-reduction process using KOH, O2, solvent, dibenzo-18-crown-6 and NaBH4, in which the oxidation is shifted toward the formation of a hydroxy compound, namely, N-benzylidene-2-hydroxybenzylamine.Oxidation in this system is a convenient preparative method for introducing a hydroxyl group into "acidic" CH bonds.
